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Abstract Optical polymer‐based integrated photonic devices are gaining interest for applications in optical packaging, biosensing, and augmented/virtual reality (AR/VR). The low refractive index of conventional organic polymers has been a barrier to realizing dense, low footprint photonic devices. The fabrication and characterization of integrated photonic devices using a new class of high refractive index polymers, chalcogenide hybrid inorganic/organic polymers (CHIPs), which possess high refractive indices and lower optical losses compared to traditional hydrocarbon‐based polymers, are reported. These optical polymers are derived from elemental sulfur via the inverse vulcanization process, which allows for inexpensive monomers to be used for these materials. A facile fabrication strategy using CHIPs via lithography is described for single‐mode optical waveguides, Y junction splitters, multimode interferometers (MMIs), and high Q factor ring resonators, along with device characterization. Furthermore, propagation losses of 0.4 dB cm−1near 1550 nm wavelength, which is the lowest measured loss in non‐fluorinated optical polymer waveguides, coupled with the benefits of low cost materials and manufacturing are reported. Ring resonators with Q factor on the order of 6 × 104and cavity finesse of 45, which are some of the highest values reported for optical polymer‐based ring resonators, are also reported.
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Phase‐Shifted Bragg Gratings from High Refractive Index Chalcogenide Hybrid Inorganic/Polymers: Fabrication and Thermo‐Optic Characterization
Abstract In this study, the first fabrication of phase‐shifted Bragg gratings utilizing chalcogenide hybrid inorganic/organic polymers (CHIPs) is presented based on poly(sulfur‐random‐(1,3‐isopropenylbenzene) to measure the thermo‐optic coefficient (TOC) of this new class of optical polymers. The unique properties ofCHIPs, such as high index contrast and low optical losses, are leveraged to fabricate Bragg gratings that enable precise determination of the TOC and glass transition temperature (Tg) of these polymers. The optical measurement introduces a novel technique to measure the TOC and Tgof optical polymers which can be difficult to determine using traditional methods such as differential scanning calorimetry (DSC) after fabrication into photonic device constructs. The findings demonstrate thatCHIPs exhibit low thermo‐optic (TO) effects, making them exceptionally well‐suited for the development of thermally stable photonic integrated circuits.
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- PAR ID:
- 10518250
- Publisher / Repository:
- Wiley Blackwell (John Wiley & Sons)
- Date Published:
- Journal Name:
- Advanced Optical Materials
- Volume:
- 12
- Issue:
- 29
- ISSN:
- 2195-1071
- Format(s):
- Medium: X
- Sponsoring Org:
- National Science Foundation
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