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Title: Magnetic Assembly of Magnetite/Perovskite Hybrid Nanorods for Circularly Polarized Luminescence
Abstract Magnetic fields are uniquely valuable for creating colloidal nanostructured materials, not only providing a means for controlled synthesis but also guiding their self‐assembly into distinct superstructures. In this study, a magnetothermal process for synthesizing hybrid nanostructures comprising ferrimagnetic magnetite nanorods coated with fluorescent perovskite nanocrystals is reported and their magnetic assembly into superstructures capable of emitting linear and circularly polarized light are demonstrated. Under UV excitation, the superstructures assembled in a liner magnetic field produce linear polarized luminescence, and those assembled in a chiral magnetic field exhibit strong circularly polarized luminescence (CPL) with aglumvalue up to 0.44 (±0.004). The CPL is believed to originate from the dipolar interaction between neighboring perovskite nanocrystals attached to the chiral assemblies and the chiral‐selective absorption of the perovskite emission by the magnetite phase. The magnetic synthesis and assembly approaches and the resulting distinctive chiral superstructures are anticipated to open up new avenues for designing diverse functional chiroptical devices.  more » « less
Award ID(s):
2203972
PAR ID:
10523307
Author(s) / Creator(s):
; ; ; ; ; ; ; ; ; ;
Publisher / Repository:
Wiley
Date Published:
Journal Name:
Advanced Functional Materials
ISSN:
1616-301X
Page Range / eLocation ID:
2403629
Format(s):
Medium: X
Sponsoring Org:
National Science Foundation
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