Observation of a new type of nanoscale ferroelectric domains, termed as “bubble domains”—laterally confined spheroids of sub‐10 nm size with local dipoles self‐aligned in a direction opposite to the macroscopic polarization of a surrounding ferroelectric matrix—is reported. The bubble domains appear in ultrathin epitaxial PbZr0.2Ti0.8O3/SrTiO3/PbZr0.2Ti0.8O3ferroelectric sandwich structures due to the interplay between charge and lattice degrees of freedom. The existence of the bubble domains is revealed by high‐resolution piezoresponse force microscopy (PFM), and is corroborated by aberration‐corrected atomic‐resolution scanning transmission electron microscopy mapping of the polarization displacements. An incommensurate phase and symmetry breaking is found within these domains resulting in local polarization rotation and hence impart a mixed Néel–Bloch‐like character to the bubble domain walls. PFM hysteresis loops for the bubble domains reveal that they undergo an irreversible phase transition to cylindrical domains under the electric field, accompanied by a transient rise in the electromechanical response. The observations are in agreement with ab‐initio‐based calculations, which reveal a very narrow window of electrical and elastic parameters that allow the existence of bubble domains. The findings highlight the richness of polar topologies possible in ultrathin ferroelectric structures and bring forward the prospect of emergent functionalities due to topological transitions.
This content will become publicly available on September 26, 2025
- Award ID(s):
- 2132105
- PAR ID:
- 10554632
- Publisher / Repository:
- Nature
- Date Published:
- Journal Name:
- Nature Nanotechnology
- ISSN:
- 1748-3387
- Format(s):
- Medium: X
- Sponsoring Org:
- National Science Foundation
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