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This content will become publicly available on August 30, 2025

Title: A first proof of knot localization for polymers in a nanochannel
Abstract Based on polymer scaling theory and numerical evidence, Orlandini, Tesi, Janse van Rensburg and Whittington conjectured in 1996 that the limiting entropy of knot-typeKlattice polygons is the same as that for unknot polygons, and that the entropic critical exponent increases by one for each prime knot in the knot decomposition ofK. This Knot Entropy (KE) conjecture is consistent with the idea that for unconfined polymers, knots occur in a localized way (the knotted part is relatively small compared to polymer length). For full confinement (to a sphere or box), numerical evidence suggests that knots are much less localized. Numerical evidence for nanochannel or tube confinement is mixed, depending on how the size of a knot is measured. Here we outline the proof that the KE conjecture holds for polygons in the × 2 × 1 lattice tube and show that knotting is localized when a connected-sum measure of knot size is used. Similar results are established for linked polygons. This is the first model for which the knot entropy conjecture has been proved.  more » « less
Award ID(s):
1934568
PAR ID:
10555432
Author(s) / Creator(s):
; ; ; ; ; ;
Publisher / Repository:
IOP Publishing
Date Published:
Journal Name:
Journal of Physics A: Mathematical and Theoretical
Volume:
57
Issue:
38
ISSN:
1751-8113
Page Range / eLocation ID:
38LT01
Format(s):
Medium: X
Sponsoring Org:
National Science Foundation
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