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1. Valence, charge transfer, and orbital-dependent correlation in bilayer nickelates ${\mathrm{Nd}}_3{\mathrm{Ni}}_2{\mathrm{O}}_7$

   https://doi.org/10.1103/PhysRevB.111.165101  

   Takegami, Daisuke; Okauchi, Takaki; Morales, Edgar Abarca; Fujinuma, Koto; Furo, Mizuki; Yoshimura, Masato; Tsuei, Ku-Ding; Pan, Grace A; Segedin, Dan Ferenc; Song, Qi; et al (April 2025, Physical Review B)

   We examine the bulk electronic structure of ${\mathrm{Nd}}_3{\mathrm{Ni}}_2{\mathrm{O}}_7$using Ni $2p$core-level hard x-ray photoemission spectroscopy combined with density functional theory $+$dynamical mean-field theory. Our results reveal a large deviation of the Ni $3d$occupation from the formal ${\mathrm{Ni}}^{2.5+}$valency, highlighting the importance of the charge transfer from oxygen ligands. We find that the dominant $d^8$configuration is accompanied by nearly equal contributions from $d^7$and $d^9$states, exhibiting an unusual valence state among Ni-based oxides. Finally, we discuss the Ni $d_{x^2-y^2}$and $d_{z^2}$orbital-dependent hybridization, correlation and local spin dynamics. Published by the American Physical Society2025 

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2. Anomalous Landau Level Gaps Near Magnetic Transitions in Monolayer ${\mathrm{WSe}}_2$

   https://doi.org/10.1103/PhysRevX.14.031018  

   Foutty, Benjamin A; Calvera, Vladimir; Han, Zhaoyu; Kometter, Carlos R; Liu, Song; Watanabe, Kenji; Taniguchi, Takashi; Hone, James C; Kivelson, Steven A; Feldman, Benjamin E (August 2024, Physical Review X)

   First-order phase transitions produce abrupt changes to the character of both ground and excited electronic states. Here we conduct electronic compressibility measurements to map the spin phase diagram and Landau level (LL) energies of monolayer ${\mathrm{WSe}}_2$in a magnetic field. We resolve a sequence of first-order phase transitions between completely spin-polarized LLs and states with LLs of both spins. Unexpectedly, the LL gaps are roughly constant over a wide range of magnetic fields below the transitions, which we show reflects spin-polarized ground states with opposite spin excitations. These transitions also extend into compressible regimes, with a sawtooth boundary between full and partial spin polarization. We link these observations to the important influence of LL filling on the exchange energy beyond a smooth density-dependent contribution. Our results show that ${\mathrm{WSe}}_2$realizes a unique hierarchy of energy scales where such effects induce reentrant magnetic phase transitions tuned by density and magnetic field. Published by the American Physical Society2024 

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3. Controllable suppression of the unconventional superconductivity in bulk and thin-film ${\mathrm{Sr}}_2{\mathrm{RuO}}_4$ via high-energy electron irradiation

   https://doi.org/10.1103/PhysRevResearch.6.033178  

   Ruf, Jacob P; Noad, Hilary_M L; Grasset, Romain; Miao, Ludi; Zhakina, Elina; McGuinness, Philippa H; Nair, Hari P; Schreiber, Nathaniel J; Kikugawa, Naoki; Sokolov, Dmitry; et al (August 2024, Physical Review Research)

   In bulk ${\mathrm{Sr}}_2{\mathrm{RuO}}_4$, the strong sensitivity of the superconducting transition temperature $T_{\text{c}}$to nonmagnetic impurities provides robust evidence for a superconducting order parameter that changes sign around the Fermi surface. In superconducting epitaxial thin-film ${\mathrm{Sr}}_2{\mathrm{RuO}}_4$, the relationship between $T_{\text{c}}$and the residual resistivity ${\rho }_0$, which in bulk samples is taken to be a proxy for the low-temperature elastic scattering rate, is far less clear. Using high-energy electron irradiation to controllably introduce point disorder into bulk single-crystal and thin-film ${\mathrm{Sr}}_2{\mathrm{RuO}}_4$, we show that $T_{\text{c}}$is suppressed in both systems at nearly identical rates. This suggests that part of ${\rho }_0$in films comes from defects that do not contribute to superconducting pairbreaking and establishes a quantitative link between the superconductivity of bulk and thin-film samples. Published by the American Physical Society2024 

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4. State selectivity in core ionization of methane

   https://doi.org/10.1103/PhysRevResearch.7.L022021  

   Rajput, J; Stindl, J; Cassimi, A; Gervais, B; Kircher, M; Kastirke, G; McGinnis, O D; Enoki, R; Williams, J B; Davis, V; et al (April 2025, Physical Review Research)

   A clear experimental signature of the population of the lowest triplet state ${}^{3}T_1$of the methane dication is identified in a photoionization experiment. This state is populated only in valence ionization and is absent when the dication is formed by core ionization followed by Auger-Meitner decay. For valence ionization, the total internal energy of the ${\mathrm{CH}}_3^{+}$fragment, formed during the deprotonation of ${\mathrm{CH}}_4{}^{2+}$, is evaluated. Notably, the distribution of this internal energy peaks at the same value regardless of the initially populated electronic state of ${\mathrm{CH}}_4{}^{2+}$. We find that excited electronic states of ${\mathrm{CH}}_3^{+}$are predominantly populated with significant rovibrational excitation. Published by the American Physical Society2025 

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5. Decoupling the electronic gap from the spin Chern number in spin-resolved topological insulators

   https://doi.org/10.1103/PhysRevB.110.214211  

   Tyner, Alexander C; Grindall, Cormac; Pixley, J H (December 2024, Physical Review B)

   In two-dimensional topological insulators, a disorder-induced topological phase transition is typically identified with an Anderson localization transition at the Fermi energy. However, in ${\mathbb{Z}}_2$trivial, spin-resolved topological insulators it is the spectral gap of the spin spectrum, in addition to the bulk mobility gap, which protects the nontrivial topology of the ground state. In this work, we show that these two gaps, the bulk electronic and spin gap, can evolve distinctly on the introduction of quenched short-ranged disorder and that an odd-quantized spin Chern number topologically protects states below the Fermi energy from localization. This decoupling leads to a unique situation in which an Anderson localization transition occurs below the Fermi energy at the topological transition. Furthermore, the presence of topologically protected extended bulk states nontrivial bulk topology typically implies the existence of protected boundary modes. We demonstrate the absence of protected boundary modes in the Hamiltonian and yet the edge modes in the eigenstates of the projected spin operator survive. Our work thus provides evidence that a nonzero spin-Chern number, in the absence of a nontrivial ${\mathbb{Z}}_2$index, does not demand the existence of protected boundary modes at finite or zero energy. Published by the American Physical Society2024 

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