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1. Spectroscopic evidence of flat bands in breathing kagome semiconductor Nb3I8

   https://doi.org/10.1038/s43246-022-00318-3  

   Regmi, Sabin; Fernando, Tharindu; Zhao, Yuzhou; Sakhya, Anup Pradhan; Dhakal, Gyanendra; Bin Elius, Iftakhar; Vazquez, Hector; Denlinger, Jonathan D.; Yang, Jihui; Chu, Jiun-Haw; et al (December 2022, Communications Materials)

   Abstract Kagome materials have become solid grounds to study the interplay among geometry, topology, correlation, and magnetism. Recently, niobium halide semiconductors Nb 3 X 8 ( X  = Cl, Br, I) have been predicted to be two-dimensional magnets and these materials are also interesting for their breathing kagome geometry. However, experimental electronic structure studies of these promising materials are still lacking. Here, we report the spectroscopic evidence of flat and weakly dispersing bands in breathing-kagome semiconductor Nb 3 I 8 around 500 meV binding energy, which is well supported by our first-principles calculations. These bands originate from the breathing kagome lattice of niobium atoms and have niobium d -orbital character. They are found to be sensitive to the polarization of the incident photon beam. Our study provides insight into the electronic structure and flat band topology in an exfoliable kagome semiconductor, thereby providing an important platform to understand the interaction of geometry and electron correlations in two-dimensional materials. 

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2. Accessing bands with extended quantum metric in kagome Cs ₂ Ni ₃ S ₄ through soft chemical processing

   https://doi.org/10.1126/sciadv.adl1103  

   Villalpando, Graciela; Jovanovic, Milena; Hoff, Brianna; Jiang, Yi; Singha, Ratnadwip; Yuan, Fang; Hu, Haoyu; Călugăru, Dumitru; Mathur, Nitish; Khoury, Jason F; et al (September 2024, Science Advances)

   Flat bands that do not merely arise from weak interactions can produce exotic physical properties, such as superconductivity or correlated many-body effects. The quantum metric can differentiate whether flat bands will result in correlated physics or are merely dangling bonds. A potential avenue for achieving correlated flat bands involves leveraging geometrical constraints within specific lattice structures, such as the kagome lattice; however, materials are often more complex. In these cases, quantum geometry becomes a powerful indicator of the nature of bands with small dispersions. We present a simple, soft-chemical processing route to access a flat band with an extended quantum metric below the Fermi level. By oxidizing Ni-kagome material Cs₂Ni₃S₄to CsNi₃S₄, we see a two orders of magnitude drop in the room temperature resistance. However, CsNi₃S₄is still insulating, with no evidence of a phase transition. Using experimental data, density functional theory calculations, and symmetry analysis, our results suggest the emergence of a correlated insulating state of unknown origin. 

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3. Electronic nature of the pseudogap in electron-doped Sr2IrO4

   https://doi.org/10.1038/s41535-022-00467-1  

   Peng, Shuting; Lane, Christopher; Hu, Yong; Guo, Mingyao; Chen, Xiang; Sun, Zeliang; Hashimoto, Makoto; Lu, Donghui; Shen, Zhi-Xun; Wu, Tao; et al (December 2022, npj Quantum Materials)

   Abstract In high-temperature ( T c ) cuprate superconductors, many exotic phenomena are rooted in the enigmatic pseudogap state, which has been interpreted as consisting of preformed Cooper pairs or competing orders or a combination thereof. Observation of pseudogap phenomenologically in electron-doped Sr 2 IrO 4 —the 5d electron counterpart of the cuprates, has spurred intense interest in the strontium iridates as a testbed for exploring the exotic physics of the cuprates. Here, we examine the pseudogap state of electron-doped Sr 2 IrO 4 by angle-resolved photoemission spectroscopy (ARPES) and parallel theoretical modeling. Our analysis demonstrates that the pseudogap state of Sr 2 IrO 4 appears without breaking the particle–hole symmetry or inducing spectral broadening which are telltale signatures of competing orders in the cuprates. We find quasiparticle dispersion and its temperature dependence in the pseudogap state of Sr 2 IrO 4 to point to an electronic order with a zero scattering wave vector and limited correlation length. Particle–hole symmetric preformed Cooper pairs are discussed as a viable mechanism for such an electronic order. The potential roles of incommensurate density waves are also discussed. 

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4. Spin-valley locking and bulk quantum Hall effect in a noncentrosymmetric Dirac semimetal BaMnSb2

   https://doi.org/10.1038/s41467-021-24369-1  

   Liu, J. Y.; Yu, J.; Ning, J. L.; Yi, H. M.; Miao, L.; Min, L. J.; Zhao, Y. F.; Ning, W.; Lopez, K. A.; Zhu, Y. L.; et al (December 2021, Nature Communications)

   null (Ed.)

   Abstract Spin-valley locking in monolayer transition metal dichalcogenides has attracted enormous interest, since it offers potential for valleytronic and optoelectronic applications. Such an exotic electronic state has sparsely been seen in bulk materials. Here, we report spin-valley locking in a Dirac semimetal BaMnSb 2 . This is revealed by comprehensive studies using first principles calculations, tight-binding and effective model analyses, angle-resolved photoemission spectroscopy measurements. Moreover, this material also exhibits a stacked quantum Hall effect (QHE). The spin-valley degeneracy extracted from the QHE is close to 2. This result, together with the Landau level spin splitting, further confirms the spin-valley locking picture. In the extreme quantum limit, we also observed a plateau in the z -axis resistance, suggestive of a two-dimensional chiral surface state present in the quantum Hall state. These findings establish BaMnSb 2 as a rare platform for exploring coupled spin and valley physics in bulk single crystals and accessing 3D interacting topological states. 

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5. Observation of momentum-dependent charge density wave gap in a layered antiferromagnet GdTe3

   https://doi.org/10.1038/s41598-023-44851-8  

   Regmi, Sabin; Bin Elius, Iftakhar; Sakhya, Anup Pradhan; Jeff, Dylan; Sprague, Milo; Mondal, Mazharul Islam; Jarrett, Damani; Valadez, Nathan; Agosto, Alexis; Romanova, Tetiana; et al (December 2023, Scientific Reports)

   Abstract Charge density wave (CDW) ordering has been an important topic of study for a long time owing to its connection with other exotic phases such as superconductivity and magnetism. The$$R{\textrm{Te}}_{3}$$ $R{\text{Te}}_3$(R= rare-earth elements) family of materials provides a fertile ground to study the dynamics of CDW in van der Waals layered materials, and the presence of magnetism in these materials allows to explore the interplay among CDW and long range magnetic ordering. Here, we have carried out a high-resolution angle-resolved photoemission spectroscopy (ARPES) study of a CDW material$${\textrm{Gd}}{\textrm{Te}}_{3}$$ $\text{Gd}{\text{Te}}_3$, which is antiferromagnetic below$$\sim \mathrm {12~K}$$ $\sim 12K$, along with thermodynamic, electrical transport, magnetic, and Raman measurements. Our ARPES data show a two-fold symmetric Fermi surface with both gapped and ungapped regions indicative of the partial nesting. The gap is momentum dependent, maximum along$${\overline{\Gamma }}-\mathrm{\overline{Z}}$$ $\overline{\Gamma }-\overline{Z}$and gradually decreases going towards$${\overline{\Gamma }}-\mathrm{\overline{X}}$$ $\overline{\Gamma }-\overline{X}$. Our study provides a platform to study the dynamics of CDW and its interaction with other physical orders in two- and three-dimensions. 

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