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Amphiphilic complexes with luminescent rare earth metal ions suitable for Lanmuir-Blodgett (LB) deposition have been synthesized. LB monolayers with closely packed Eu complexes deposited directly on silver demonstrate significant far-field emission in contrast to the theoretical predictions of full quenching. Angular radiation and polarization patterns of the electric and magnetic dipole emission of Eu3+point to a high excitation efficiency of surface plasmon polaritons. Different luminescent behavior of closely packed emitters in comparison to diluted systems is tentatively attributed to the collective state of emitters in LB layers formed via near-field coupling with surface plasmons.
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New amphiphilic complexes with luminescent rare-earth ions
Abstract Organic compounds containing luminous rare-earth ions are of interest for numerous nanophotonic and plasmonic applications, including nanoscale lasers, biosensors, and optical magnetism studies. Optical studies of Eu3+complexes revealed that ultra-thin LB monolayers are highly luminescent even when deposited directly on plasmonic metal, which makes these materials very promising for plasmonic applications and studies, including control and enhancement of magnetic dipole emission with a plasmonic environment. In this work, we synthesize amphiphilic complexes with various rare-earth ions Nd3+, Yb3+, and DPT ligands and show that they all are suitable for monolayer or multilayer deposition with the Langmuir–Blodgett (LB) technique. Graphical abstract
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- PAR ID:
- 10575856
- Publisher / Repository:
- Cambridge University Press (CUP)
- Date Published:
- Journal Name:
- MRS Advances
- Volume:
- 10
- Issue:
- 10
- ISSN:
- 2731-5894
- Format(s):
- Medium: X Size: p. 1240-1244
- Size(s):
- p. 1240-1244
- Sponsoring Org:
- National Science Foundation
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