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1. Valence, charge transfer, and orbital-dependent correlation in bilayer nickelates ${\mathrm{Nd}}_3{\mathrm{Ni}}_2{\mathrm{O}}_7$

   https://doi.org/10.1103/PhysRevB.111.165101  

   Takegami, Daisuke; Okauchi, Takaki; Morales, Edgar Abarca; Fujinuma, Koto; Furo, Mizuki; Yoshimura, Masato; Tsuei, Ku-Ding; Pan, Grace A; Segedin, Dan Ferenc; Song, Qi; et al (April 2025, Physical Review B)

   We examine the bulk electronic structure of ${\mathrm{Nd}}_3{\mathrm{Ni}}_2{\mathrm{O}}_7$using Ni $2p$core-level hard x-ray photoemission spectroscopy combined with density functional theory $+$dynamical mean-field theory. Our results reveal a large deviation of the Ni $3d$occupation from the formal ${\mathrm{Ni}}^{2.5+}$valency, highlighting the importance of the charge transfer from oxygen ligands. We find that the dominant $d^8$configuration is accompanied by nearly equal contributions from $d^7$and $d^9$states, exhibiting an unusual valence state among Ni-based oxides. Finally, we discuss the Ni $d_{x^2-y^2}$and $d_{z^2}$orbital-dependent hybridization, correlation and local spin dynamics. Published by the American Physical Society2025 

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2. Controllable suppression of the unconventional superconductivity in bulk and thin-film ${\mathrm{Sr}}_2{\mathrm{RuO}}_4$ via high-energy electron irradiation

   https://doi.org/10.1103/PhysRevResearch.6.033178  

   Ruf, Jacob P; Noad, Hilary_M L; Grasset, Romain; Miao, Ludi; Zhakina, Elina; McGuinness, Philippa H; Nair, Hari P; Schreiber, Nathaniel J; Kikugawa, Naoki; Sokolov, Dmitry; et al (August 2024, Physical Review Research)

   In bulk ${\mathrm{Sr}}_2{\mathrm{RuO}}_4$, the strong sensitivity of the superconducting transition temperature $T_{\text{c}}$to nonmagnetic impurities provides robust evidence for a superconducting order parameter that changes sign around the Fermi surface. In superconducting epitaxial thin-film ${\mathrm{Sr}}_2{\mathrm{RuO}}_4$, the relationship between $T_{\text{c}}$and the residual resistivity ${\rho }_0$, which in bulk samples is taken to be a proxy for the low-temperature elastic scattering rate, is far less clear. Using high-energy electron irradiation to controllably introduce point disorder into bulk single-crystal and thin-film ${\mathrm{Sr}}_2{\mathrm{RuO}}_4$, we show that $T_{\text{c}}$is suppressed in both systems at nearly identical rates. This suggests that part of ${\rho }_0$in films comes from defects that do not contribute to superconducting pairbreaking and establishes a quantitative link between the superconductivity of bulk and thin-film samples. Published by the American Physical Society2024 

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3. Orbital Ingredients and Persistent Dirac Surface State for the Topological Band Structure in ${\mathrm{FeTe}}_{0.55}{\mathrm{Se}}_{0.45}$

   https://doi.org/10.1103/PhysRevX.14.021043  

   Li, Y-F; Chen, S-D; García-Díez, M; Iraola, M I; Pfau, H; Zhu, Y-L; Mao, Z-Q; Chen, T; Yi, M; Dai, P-C; et al (June 2024, Physical Review X)

   ${\mathrm{FeTe}}_{0.55}{\mathrm{Se}}_{0.45}$(FTS) occupies a special spot in modern condensed matter physics at the intersections of electron correlation, topology, and unconventional superconductivity. The bulk electronic structure of FTS is predicted to be topologically nontrivial due to the band inversion between the $d_{xz}$and $p_z$bands along $\mathrm{\Gamma }\text{−}Z$. However, there remain debates in both the authenticity of the Dirac surface states (DSSs) and the experimental deviations of band structure from the theoretical band inversion picture. Here we resolve these debates through a comprehensive angle-resolved photoemission spectroscopy investigation. We first observe a persistent DSS independent of $k_z$. Then, by comparing FTS with FeSe, which has no band inversion along $\mathrm{\Gamma }\text{−}Z$, we identify the spectral weight fingerprint of both the presence of the $p_z$band and the inversion between the $d_{xz}$and $p_z$bands. Furthermore, we propose a renormalization scheme for the band structure under the framework of a tight-binding model preserving crystal symmetry. Our results highlight the significant influence of correlation on modifying the band structure and make a strong case for the existence of topological band structure in this unconventional superconductor. Published by the American Physical Society2024 

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4. Absence of $E_{2g}$ Nematic Instability and Dominant $A_{1g}$ Response in the Kagome Metal ${\mathrm{CsV}}_3{\mathrm{Sb}}_5$

   https://doi.org/10.1103/PhysRevX.14.031015  

   Liu, Zhaoyu; Shi, Yue; Jiang, Qianni; Rosenberg, Elliott W; DeStefano, Jonathan M; Liu, Jinjin; Hu, Chaowei; Zhao, Yuzhou; Wang, Zhiwei; Yao, Yugui; et al (July 2024, Physical Review X)

   Ever since the discovery of the charge density wave (CDW) transition in the kagome metal ${\mathrm{CsV}}_3{\mathrm{Sb}}_5$, the nature of its symmetry breaking has been under intense debate. While evidence suggests that the rotational symmetry is already broken at the CDW transition temperature ( $T_{\mathrm{CDW}}$), an additional electronic nematic instability well below $T_{\mathrm{CDW}}$has been reported based on the diverging elastoresistivity coefficient in the anisotropic channel ( $m_{E_{2g}}$). Verifying the existence of a nematic transition below $T_{\mathrm{CDW}}$is not only critical for establishing the correct description of the CDW order parameter, but also important for understanding low-temperature superconductivity. Here, we report elastoresistivity measurements of ${\mathrm{CsV}}_3{\mathrm{Sb}}_5$using three different techniques probing both isotropic and anisotropic symmetry channels. Contrary to previous reports, we find the anisotropic elastoresistivity coefficient $m_{E_{2g}}$is temperature independent, except for a step jump at $T_{\mathrm{CDW}}$. The absence of nematic fluctuations is further substantiated by measurements of the elastocaloric effect, which show no enhancement associated with nematic susceptibility. On the other hand, the symmetric elastoresistivity coefficient $m_{A_{1g}}$increases below $T_{\mathrm{CDW}}$, reaching a peak value of 90 at $T^{*}=20\mathrm{K}$. Our results strongly indicate that the phase transition at $T^{*}$is not nematic in nature and the previously reported diverging elastoresistivity is due to the contamination from the $A_{1g}$channel. Published by the American Physical Society2024 

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5. Unconventional superconducting phase diagram of monolayer ${\mathrm{WTe}}_2$

   https://doi.org/10.1103/PhysRevResearch.7.013224  

   Song, Tiancheng; Jia, Yanyu; Yu, Guo; Tang, Yue; Uzan, Ayelet J; Zheng, Zhaoyi Joy; Guan, Haosen; Onyszczak, Michael; Singha, Ratnadwip; Gui, Xin; et al (February 2025, Physical Review Research)

   The existence of a quantum critical point (QCP) and fluctuations around it are believed to be important for understanding the phase diagram in unconventional superconductors such as cuprates, iron pnictides, and heavy fermion superconductors. However, the QCP is usually buried deep within the superconducting dome and is difficult to investigate. The connection between quantum critical fluctuations and superconductivity remains an outstanding problem in condensed matter. Here combining both electrical transport and Nernst experiments, we explicitly demonstrate the onset of superconductivity at an unconventional QCP in gate-tuned monolayer tungsten ditelluride $\left({\mathrm{WTe}}_2\right)$, with features incompatible with the conventional Bardeen-Cooper-Schrieffer scenario. The results lead to a superconducting phase diagram that is distinguished from other known superconductors. Two distinct gate-tuned quantum phase transitions are observed at the ends of the superconducting dome. We find that quantum fluctuations around the QCP of the underdoped regime are essential for understanding how the monolayer superconductivity is established. The unconventional phase diagram we report here illustrates a previously unknown relation between superconductivity and QCP. Published by the American Physical Society2025 

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