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1. Large magnetocapacitance beyond 420% in epitaxial magnetic tunnel junctions with an MgAl2O4 barrier

   https://doi.org/10.1038/s41598-022-11545-6  

   Sato, Kenta; Sukegawa, Hiroaki; Ogata, Kentaro; Xiao, Gang; Kaiju, Hideo (May 2022, Scientific Reports)

   Abstract Magnetocapacitance (MC) effect has been observed in systems where both symmetries of time-reversal and space-inversion are broken, for examples, in multiferroic materials and spintronic devices. The effect has received increasing attention due to its interesting physics and the prospect of applications. Recently, a large tunnel magnetocapacitance (TMC) of 332% at room temperature was reported using MgO-based (001)-textured magnetic tunnel junctions (MTJs). Here, we report further enhancement in TMC beyond 420% at room temperature using epitaxial MTJs with an MgAl₂O₄(001) barrier with a cation-disordered spinel structure. This large TMC is partially caused by the high effective tunneling spin polarization, resulted from the excellent lattice matching between the Fe electrodes and the MgAl₂O₄barrier. The epitaxial nature of this MTJ system sports an enhanced spin-dependent coherent tunneling effect. Among other factors leading to the large TMC are the appearance of the spin capacitance, the large barrier height, and the suppression of spin flipping through the MgAl₂O₄barrier. We explain the observed TMC by the Debye-Fröhlich modelled calculation incorporating Zhang-sigmoid formula, parabolic barrier approximation, and spin-dependent drift diffusion model. Furthermore, we predict a 1000% TMC in MTJs with a spin polarization of 0.8. These experimental and theoretical findings provide a deeper understanding on the intrinsic mechanism of the TMC effect. New applications based on large TMC may become possible in spintronics, such as multi-value memories, spin logic devices, magnetic sensors, and neuromorphic computing. 

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2. Spin Filtering with Insulating Altermagnets

   https://doi.org/10.1021/acs.nanolett.4c05672  

   Samanta, Kartik; Shao, Ding-Fu; Tsymbal, Evgeny Y (February 2025, Nano Letters)

   Altermagnetic (AM) materials have recently attracted significant interest due to their non-relativistic momentum-dependent spin splitting of their electronic band structure which may be useful for antiferromagnetic (AFM) spintronics. So far, however, most research studies have been focused on conducting properties of AM metals and semiconductors, while functional properties of AM insulators have remained largely unexplored. Here, we propose employing AM insulators (AMIs) as efficient spin-filter materials. By analyzing the complex band structure of rutile-type altermagnets MF2 (M = Fe, Co, Ni), we demonstrate that the evanescent states in these AMIs exhibit spin- and momentum-dependent decay rates resulting in momentum-dependent spin polarization of the tunneling current. Using a model of spin-filter tunneling across a spin-dependent potential barrier, we estimate the TMR effect in spin-filter magnetic tunnel junctions (SF-MTJs) that include two magnetically decoupled MF2 (001) barrier layers. We predict a sizable spin-filter TMR ratio of about 150-170% in SF-MTJs based on AMIs CoF2 and NiF2 if the Fermi energy is tuned to be close to the valence band maximum. Our results demonstrate that AMIs provide a viable alternative to conventional spin-filter materials, potentially advancing the development of next-generation AFM spintronic devices. 

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3. Spin-neutral currents for spintronics

   https://doi.org/10.1038/s41467-021-26915-3  

   Shao, Ding-Fu; Zhang, Shu-Hui; Li, Ming; Eom, Chang-Beom; Tsymbal, Evgeny Y. (December 2021, Nature Communications)

   Abstract Electric currents carrying a net spin polarization are widely used in spintronics, whereas globally spin-neutral currents are expected to play no role in spin-dependent phenomena. Here we show that, in contrast to this common expectation, spin-independent conductance in compensated antiferromagnets and normal metals can be efficiently exploited in spintronics, provided their magnetic space group symmetry supports a non-spin-degenerate Fermi surface. Due to their momentum-dependent spin polarization, such antiferromagnets can be used as active elements in antiferromagnetic tunnel junctions (AFMTJs) and produce a giant tunneling magnetoresistance (TMR) effect. Using RuO₂as a representative compensated antiferromagnet exhibiting spin-independent conductance along the [001] direction but a non-spin-degenerate Fermi surface, we design a RuO₂/TiO₂/RuO₂(001) AFMTJ, where a globally spin-neutral charge current is controlled by the relative orientation of the Néel vectors of the two RuO₂electrodes, resulting in the TMR effect as large as ~500%. These results are expanded to normal metals which can be used as a counter electrode in AFMTJs with a single antiferromagnetic layer or other elements in spintronic devices. Our work uncovers an unexplored potential of the materials with no global spin polarization for utilizing them in spintronics. 

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4. Large and tunable magnetoresistance in van der Waals ferromagnet/semiconductor junctions

   https://doi.org/10.1038/s41467-023-41077-0  

   Zhu, Wenkai; Zhu, Yingmei; Zhou, Tong; Zhang, Xianpeng; Lin, Hailong; Cui, Qirui; Yan, Faguang; Wang, Ziao; Deng, Yongcheng; Yang, Hongxin; et al (December 2023, Nature Communications)

   Magnetic tunnel junctions (MTJs) with conventional bulk ferromagnets separated by a nonmagnetic insulating layer are key building blocks in spintronics for magnetic sensors and memory. A radically different approach of using atomically-thin van der Waals (vdW) materials in MTJs is expected to boost their figure of merit, the tunneling magnetoresistance (TMR), while relaxing the lattice-matching requirements from the epitaxial growth and supporting high-quality integration of dissimilar materials with atomically-sharp interfaces. We report TMR up to 192% at 10 K in all-vdW Fe3GeTe2/GaSe/Fe3GeTe2 MTJs. Remarkably, instead of the usual insulating spacer, this large TMR is realized with a vdW semiconductor GaSe. Integration of semiconductors into the MTJs offers energy-band-tunability, bias dependence, magnetic proximity effects, and spin-dependent optical-selection rules. We demonstrate that not only the magnitude of the TMR is tuned by the semiconductor thickness but also the TMR sign can be reversed by varying the bias voltages, enabling modulation of highly spin-polarized carriers in vdW semiconductors. 

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5. Antiferromagnetic tunnel junctions for spintronics

   https://doi.org/10.1038/s44306-024-00014-7  

   Shao, Ding-Fu; Tsymbal, Evgeny Y (December 2024, npj Spintronics)

   Abstract Antiferromagnetic (AFM) spintronics has emerged as a subfield of spintronics, where an AFM Néel vector is used as a state variable. Efficient electric control and detection of the Néel vector are critical for spintronic applications. This review article features fundamental properties of AFM tunnel junctions (AFMTJs) as spintronic devices where such electric control and detection can be realized. We emphasize critical requirements for observing a large tunneling magnetoresistance (TMR) effect in AFMTJs with collinear and noncollinear AFM electrodes, such as a momentum-dependent spin polarization and Néel spin currents. We further discuss spin torques in AFMTJs that are capable of Néel vector switching. Overall, AFMTJs have potential to become a new standard for spintronics providing larger magnetoresistive effects, few orders of magnitude faster switching speed, and much higher packing density than conventional magnetic tunnel junctions (MTJs). 

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