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Title: Flux Growth of La 3 MC 2 ( M  = Sb, Bi, Te), a New Family of Ternary Carbides
Reactions of carbon with a heavy main group metal (M = Sb, Bi, or Te) in an excess of lanthanum/nickel eutectic flux lead to formation of a family of carbide compounds La3MC2with a new structure type. The monoclinic structure features C24−anions octahedrally coordinated by six La3+cations, andManions surrounded by 8 La3+cations. These compounds are not charge‐balanced and lie on the border between intermetallic carbides and mixed anion salts. Density of states calculations show a pseudogap at the Fermi level for La3BiC2, which indicates that this compound is a poor metal with optimized LaBi bonding interactions.  more » « less
Award ID(s):
2126077
PAR ID:
10653237
Author(s) / Creator(s):
 ;  ;  ;  ;  ;  
Publisher / Repository:
Wiley
Date Published:
Journal Name:
Zeitschrift für anorganische und allgemeine Chemie
Volume:
651
Issue:
10
ISSN:
0044-2313
Format(s):
Medium: X
Sponsoring Org:
National Science Foundation
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