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Abstract Sub-Neptune exoplanets may have thick hydrogen envelopes and therefore develop a high-pressure interface between hydrogen and the underlying silicates/metals. Some sub-Neptunes may convert to super-Earths via massive gas loss. If hydrogen chemically reacts with oxides and metals at high pressures and temperatures (P−T), it could impact the structure and composition of the cores and atmospheres of sub-Neptunes and super-Earths. While H2gas is a strong reducing agent at low pressures, the behavior of hydrogen is unknown at theP−Texpected for sub-Neptunes’ interiors, where hydrogen is a dense supercritical fluid. Here we report experimental results of reactions between ferrous/ferric oxides and hydrogen at 20–40 GPa and 1000–4000 K utilizing the pulsed laser-heated diamond-anvil cell combined with synchrotron X-ray diffraction. Under these conditions, hydrogen spontaneously strips iron off the oxides, forming Fe-H alloys and releasing oxygen to the hydrogen medium. In a planetary context where this reaction may occur, the Fe-H alloy may sink to the metallic part of the core, while released oxygen may stabilize as water in the silicate layer, providing a mechanism to ingas hydrogen to the deep interiors of sub-Neptunes. Water produced from the redox reaction can also partition to the atmosphere of sub-Neptunes, which has important implications for understanding the composition of their atmospheres. In addition, super-Earths converted from sub-Neptunes may contain a large amount of hydrogen and water in their interiors (at least a few wt% H2O). This is distinct from smaller rocky planets, which were formed relatively dry (likely a few hundredths wt% H2O).
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This content will become publicly available on September 9, 2026
Formation of Organic Hazes in CO 2 -rich Sub-Neptune Atmospheres within the Graphite Stability Regime
Abstract Super-Earths and sub-Neptunes are the most common exoplanets, with a “radius valley” suggesting that super-Earths may form by shedding sub-Neptunes’ gaseous envelopes. Exoplanets that lie closer to the super-Earth side of the valley are more likely to have lost a significant fraction of their original H/He envelopes and become enriched in heavier elements, with CO2gaining in abundance. It remains unclear which types of haze would form in such atmospheres, potentially significantly affecting spectroscopic observations. To investigate this, we performed laboratory simulations of two CO2-rich gas mixtures (with 2000 times solar metallicity at 300 and 500 K). We found that under plasma irradiation organic hazes were produced at both temperatures, with a higher haze production rate at 300 K, probably because condensation occurs more readily at lower temperature. Gas-phase analysis demonstrates the formation of various hydrocarbons, oxygen- and nitrogen-containing species, including reactive gas precursors like C2H4, CH2O, and HCN, for haze formation. The compositional analysis of the haze particles reveals various functional groups and molecular formulas in both samples. The 500 K haze sample has larger average molecular sizes, a higher degree of unsaturation with more double or triple bonds present, and higher nitrogen content incorporated as N–H and C=N bonds, indicating different haze formation pathways. These findings not only improve the haze formation theories in CO2-rich exoplanet atmospheres but also offer important implications for the interpretation of future observational data.
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- Award ID(s):
- 2206245
- PAR ID:
- 10656899
- Publisher / Repository:
- IOP
- Date Published:
- Journal Name:
- The Astrophysical Journal
- Volume:
- 990
- Issue:
- 2
- ISSN:
- 0004-637X
- Page Range / eLocation ID:
- 187
- Format(s):
- Medium: X
- Sponsoring Org:
- National Science Foundation
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