Abstract Patterning of quantum dots (QDs) is essential for many, especially high‐tech, applications. Here, pH tunable assembly of QDs over functional patterns prepared by electrohydrodynamic jet printing of poly(2‐vinylpyridine) is presented. The selective adsorption of QDs from water dispersions is mediated by the electrostatic interaction between the ligand composed of 3‐mercaptopropionic acid and patterned poly(2‐vinylpyridine). The pH of the dispersion provides tunability at two levels. First, the adsorption density of QDs and fluorescence from the patterns can be modulated for pH > ≈4. Second, patterned features show unique type of disintegration resulting in randomly positioned features within areas defined by the printing for pH ≤ ≈4. The first capability is useful for deterministic patterning of QDs, whereas the second one enables hierarchically structured encoding of information by generating stochastic features of QDs within areas defined by the printing. This second capability is exploited for generating addressable security labels based on unclonable features. Through image analysis and feature matching algorithms, it is demonstrated that such patterns are unclonable in nature and provide a suitable platform for anti‐counterfeiting applications. Collectively, the presented approach not only enables effective patterning of QDs, but also establishes key guidelines for addressable assembly of colloidal nanomaterials.
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Covert and Multiplexed SERS QR Codes via Inkjet Printing
ABSTRACT Covert patterns have an extra layer of security protection for anti‐counterfeiting labels as compared with the traditional overt ones. To increase the complexity and security of quick response (QR) codes, it would be valuable to make covert QR codes that will be only scannable after a certain decoding process. In this work, the use of surface‐enhanced Raman spectroscopy (SERS) is explored to fabricate covert QR codes. Through developing new Raman‐active security inks, we can prepare covert QR codes using a convenient inkjet printing method. These QR codes will not be revealed directly. They can only be decoded using a confocal Raman microscope. In addition, multiplex QR codes can be accomplished using multiple Raman probes in printing. Our results showed that the printed QR codes are covert, have strong SERS signals, and can be easily recognized after the SERS decoding. It is anticipated that there is great potential for using such covert and multiplexed SERS‐based QR codes for advanced anti‐counterfeiting applications.
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- Award ID(s):
- 2330175
- PAR ID:
- 10665497
- Publisher / Repository:
- Wiley
- Date Published:
- Journal Name:
- Journal of Raman Spectroscopy
- ISSN:
- 0377-0486
- Format(s):
- Medium: X
- Sponsoring Org:
- National Science Foundation
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