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Federated learning (FL) aims to collaboratively train a global model using local data from a network of clients. To warrant collaborative training, each federated client may expect the resulting global model to satisfy some individual requirement, such as achieving a certain loss threshold on their local data. However, in real FL scenarios, the global model may not satisfy the requirements of all clients in the network due to the data heterogeneity across clients. In this work, we explore the problem of global model appeal in FL, which we define as the total number of clients that find that the global model satisfies their individual requirements. We discover that global models trained using traditional FL approaches can result in a significant number of clients unsatisfied with the model based on their local requirements. As a consequence, we show that global model appeal can directly impact how clients participate in training and how the model performs on new clients at inference time. Our work proposes MaxFL, which maximizes the number of clients that find the global model appealing. MaxFL achieves a 22-40% and 18-50% improvement in the test accuracy of training clients and (unseen) test clients respectively, compared to a wide range of FL approaches that tackle data heterogeneity, aim to incentivize clients, and learn personalized/fair models. 

This paper investigates and compares people’s subjective impression of an office with a biophilic design and blue lighting. Existing studies have examined their influence on perception separately, but how they compare is unclear. Additionally, only a few studies have used an office setting as a case study. To address this research gap, this study collected people’s ratings and rankings of four simulated interior scenes of a private office using an online survey. The scenes include blue lighting, a biophilic design with daylight and view, a biophilic design with indoor plants, and a non-biophilic baseline with conventional white lighting. A total of 284 complete responses were collected and analyzed using a mixed-effect model. It was found that the two biophilic designs improved people’s perception of the office compared to the base case. The biophilic design with access to daylight and view outperformed the space with indoor plants in all the examined perceptual categories, specifically how the office space was perceived by participants as brighter, more comfortable, and spacious. On the contrary, the space with blue lighting decreased people’s ratings in most perceptual attributes in comparison to the baseline. The negative influence was notably significant in how lively, comfortable, bright, and appealing the space was perceived as being by participants. Subjects’ preference rankings of the four simulated office spaces showed a similar pattern. 

A series of twelve two-coordinate coinage metal, Cu, Ag and Au, complexes with carbene-metal-amide structures were prepared. The complexes all display thermal assisted delayed fluorescence (TADF) emission at room temperature from interligand charge transfer (ICT) excited state with short lifetimes (less than 2 μs) and photoluminescent quantum yields that reach near unity. Owing to the involvement of the substituents in the emissive transitions and different metal ion volume, the natural transition orbital (NTO) overlap of the emissive state can be adjusted in a wide range from 0.21 to 0.41. Investigations on the relationship between the NTO overlap of the emissive state and key TADF photophysical properties demonstrated that both singlet–triplet energy gap and radiative decay rate of S 1 state increase along with the NTO overlap exponentially. Consequently, the overall TADF radiative decay rate leads to a maximum when plotted against the NTO overlap, giving the ideal zone from 0.25 to 0.30 for high TADF radiative decay rate in this class of two-coordinate coinage metal complex luminophores. 

Solar-thermal evaporation is a promising technology for energy-efficient desalination, but salt accumulation on solar absorbers and system longevity are the major challenges that hinder its widespread application. In this study, we present a sustainable Janus wood evaporator that overcomes these challenges and achieves a record-high evaporation efficiencies in hypersaline water, one of the most difficult water sources to treat via desalination. The Janus wood evaporator has asymmetric surface wettability, where the top layer acts as a hydrophobic solar absorber with water blockage and salt resistance, while the bottom hydrophilic wood layer allows for rapid water replenishment and superior thermal insulation. An evaporation efficiency of 82.0% is achieved for 20% NaCl solution under 1 sun, and persistent salt-resistance is observed during a 10-cycle long-term test. To ensure the environmental impact of the Janus wood evaporator, for the first time, a life cycle assessment (LCA) is conducted to compare this Janus wood evaporator with the emerging Janus evaporators, indicating a functional and more sustainable opportunity for off-grid desalination and humanitarian efforts.