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We present seismic two-way traveltime depth relationships for all sites drilled by the International Ocean Discovery Program Expedition 398, Hellenic Arc Volcanic Field, using high-resolution multichannel seismic and core data. First, we filter and interpolate P-wave velocity and density data taken from (1) whole-round cores and (2) discrete measurements on half-round cores. We establish the reliability of shipboard density measurements by comparing them with in situ logging data. Using these validated measurements, we estimate acoustic impedance and synthetic seismograms. By correlating synthetic seismograms with those extracted from multichannel seismic profiles at each site, we establish time-depth relationships. We assess the quality of these relationships by examining the alignment of major lithologic boundaries with prominent unconformities or correlated conformities in the reflection seismic data. The results of this report facilitate the mapping of core data onto the multichannel seismic profiles at each site, allowing for spatial tracing of core data across the Christiana-Santorini-Kolumbo volcanic field. 

International Ocean Discovery Program (IODP) Expedition 398, Hellenic Arc Volcanic Field, recovered volcanic and nonvolcanic sediments and Messinian evaporites, as well as the nonvolcanic basement. The total recovery of about 3.3 km has the potential to significantly expand our understanding of the volcanic and tectonic history of the Christiana-Santorini-Kolumbo volcanic field and the climate history of the eastern Mediterranean. Here we report semiquantitative bulk elemental analyses of X-ray fluorescence core scans for Site U1591, drilled off Christiani Island, and Site U1599, drilled off Anafi Island, and compare these to records of natural gamma radiation that were measured aboard the R/V JOIDES Resolution. 

The objectives of International Ocean Discovery Program Expedition 398, Hellenic Arc Volcanic Field (11 December 2022 to 10 February 2023), were to study the volcanic record of the central Hellenic island arc; document the links and feedbacks between volcanism/magmatism, crustal tectonics, and sea level; investigate the processes and products of shallow submarine eruptions of silicic magma; and groundtruth the seismic stratigraphy of Santorini caldera. Reconstructing the subsidence history of the southern Aegean Sea and searching for deep life inside and outside of Santorini caldera were additional objectives. During the expedition, 10 primary and alternate sites that were originally proposed were drilled, in addition to 2 extra sites that were requested during the expedition. Outside of Santorini caldera, drilling penetrated the thick basin fills of the crustal rift system hosting the Christiana-Santorini-Kolumbo volcanic field, identifying numerous pumice and ash layers, some known from on land and others hitherto unknown, pushing back the onset of volcanism in the area into the Early Pleistocene or even Pliocene. Significant events of mass wasting into the basins, accompanied by very high sedimentation rates, were also documented. These basin sites served to groundtruth the seismic stratigraphy of the basins and open the way to unraveling relationships between volcanic activity and crustal rift pulses. Two sites of condensed sequences served to sample many volcanic layers within the detailed age-depth constraints provided mainly by biostratigraphy, as diagenetic effects complicated the magnetic reversal record significantly. Drilling penetrated the Alpine basement at three basin sites northeast of Santorini, whereas in the Christiana Basin to the southwest it penetrated a thick sequence of Messinian evaporites. Drilling inside Santorini caldera penetrated to ~120 meters below seafloor, less than planned due to hole instability issues but deep enough to groundtruth the seismic stratigraphy and sample the different layers. One intracaldera hole yielded a detailed tephra record of the history of the Kameni Islands, as well as possible evidence for deep bacterial colonies within the caldera. Despite variable recovery in the unstable pumice and ash deposits, the expedition was a significant success that may address almost all the scientific objectives once the laboratory work has been done. 

Prior to arrival on site, a decision was made to replace the original primary site (proposed Site CSK-13A) by an alternate site (proposed Site CSK-20A); hence, the latter became Site U1591. This was done to pass through a slightly more complete suite of reflectors in the 800–900 ms two-way traveltime (TWT) interval. Site U1591 is located ~8 km northwest of Christiani Island and ~20 km southwest of Santorini (Figure F1) at 514 meters below sea level (mbsl). It was drilled in three holes (U1591A–U1591C) to a maximum recovery depth of 902.7 meters below seafloor (mbsf) (all depths below seafloor are given using the core depth below seafloor, Method A [CSF-A], scale, except in Operations where the drilling depth below seafloor [DSF] scale is used). Average core recovery was similar in all three holes (U1591A= 66%; U1591B= 43%; U1591C= 58%). The drill site targeted the volcano-sedimentary fill of the Christiana Basin. This basin was believed to have formed by subsidence along an ENE–WSW fault system before the changing tectonic regime activated the current northeast–southwest rift system in which the Christiana-Santorini-Kolumbo (CSK) volcanic field lies (Tsampouraki-Kraounaki and Sakellariou, 2018; Preine et al., 2022a, 2022b). Christiana Basin is deeper than the Anhydros and Anafi Basins; its volcano-sedimentary fill potentially recorded the earlier volcanic history of the CSK volcanic field (including the products of Christiana and early Santorini), as well as younger Santorini and possibly Milos Volcano to the west along the Hellenic volcanic arc. The now-extinct Christiana Volcano produced lavas and tuffs of unknown ages (Aarburg and Frechen, 1999). An ignimbrite found on Christiani Island (one of the two small islands of Christiana Volcano), Santorini, and the nonvolcanic island of Anaphi, called the Christiani Ignimbrite, was identified (Keller et al., 2010). Six seismic units were previously recognized in the Christiana Basin (Preine et al., 2022a, 2022b; Figure F2). Site U1591 was chosen to pass through Seismic Units U1–U6, including volcaniclastics from Santorini and Christiana, and to target the top few meters of the prevolcanic basement below Unit U1. We received permission from the International Ocean Discovery Program (IODP) Environmental Protection and Safety Panel to drill to the Alpine basement at this site in an advanced piston corer/extended core barrel/rotary core barrel (APC/XCB/RCB) drilling strategy involving three holes. The aims of Site U1591 were (1) to better date the volcanic activity of Christiana using biostratigraphic and magnetostratigraphic means and determine whether the CSK volcanic field had Pliocene volcanism similar to the Milos Volcano farther west; (2) to relate the Christiana volcanism to subsidence along the ENE–WSW fault sets and to the activation of the northeast–southwest fault sets; and (3) to seek the submarine equivalent of the Christiani Ignimbrite. By using deeper coring (and seismic profiles) to reconstruct the volcanic, sedimentary, and tectonic histories of the Christiana Volcano, and possibly the Milos Volcano, we aimed to complement the Santorini and Kolumbo volcanic records of Sites U1589 and U1592 and therefore access a near-continuous time series of volcanism of the CSK volcanic field since rift inception. Site U1591 addressed scientific Objectives 1–4 and 6 of the Expedition 398 Scientific Prospectus (Druitt et al., 2022). 

Site U1595 (proposed Site CSK-08B) is located in the southern basin of the Santorini caldera at 291 meters below sea level (mbsl) (Figure F1). It was drilled in three holes (U1595A–U1595C) to a maximum recovery depth of 127.0 meters below seafloor (mbsf) (all depths below seafloor are given using the core depth below seafloor, Method A [CSF-A], scale, except in Operations where the drilling depth below seafloor [DSF] scale is used). Average hole core recoveries range 46%–77%. Site U1594 addresses the same drilling objectives and lies northeast of Site U1595. Two additional sites (U1596 and U1597) lie in the northern caldera basin. Four seismic units (S1–S4) were previously recognized in the Santorini caldera (Johnston et al., 2015; Nomikou et al., 2016) (Figure F2). Seismic Units S1–S3 were thought to consist of muds and sands from cliff mass wasting (Unit S1); compacted (possibly lithified) sandy volcaniclastics from Kameni Volcano (Unit S2); and consolidated coarse blocky intracaldera tuffs, landslide debris, and/or flood gravels (Unit S3). Unit S4 was thought to be intracaldera tuff from the Late Bronze Age eruption. The four caldera sites were planned to sample Units S1–S3; test the published correlations between the two caldera basins; penetrate below Unit S3 into Unit S4; and address scientific Objectives 1, 4, 5, and 7 of the Expedition 398 Scientific Prospectus (Druitt et al., 2022). By drilling both caldera basins and exploiting our dense seismic reflection coverage, we gained access to the 3D architecture of the entire caldera fill. We also targeted the question of why the northern basin is 100 m deeper than the southern one. Finally, we tested whether Unit S3 consisted of flood debris from the caldera flooding event (Nomikou et al., 2016) or whether it was Late Bronze Age intracaldera tuff (Johnston et al., 2015). The intracaldera sites were used for microbiological work of Objective 7. 

Site U1594 (proposed Site CSK-07B) is located in the southern basin of Santorini caldera at a water depth of 291 meters below sea level (mbsl) (Figure F1). It was drilled to a maximum recovery depth of 50.1 meters below seafloor (mbsf) in a single hole (U1594A) with 93% recovery before hole instability set in and the hole was terminated (all depths below seafloor are given using the core depth below seafloor, Method A [CSF-A] scale, except in Operations where the drilling depth below seafloor [DSF] scale is used). Site U1595 addresses the same drilling objectives and lies southwest of Site U1594. Two additional sites (U1596 and U1597) lie in the northern caldera basin. Four seismic units have been recognized in the caldera (Johnston et al., 2015; Nomikou et al., 2016) (Figure F2). They were thought to consist of muds and sands from cliff mass wasting (Seismic Unit S1); compacted (possibly lithified) sandy volcaniclastics from Kameni Volcano (Unit S2); and consolidated coarse blocky intracaldera tuffs, landslide debris, and/or flood gravels (Unit S3). Unit S4 was thought to be intracaldera tuff from the Late Bronze Age eruption. The four caldera sites were planned to sample Units S1–S3; test the published correlations between the two caldera basins; penetrate below Unit S3 into Unit S4; and address scientific Objectives 1, 4, 5, and 7 of the Expedition 398 Scientific Prospectus (Druitt et al., 2022). By drilling both caldera basins and exploiting our dense seismic reflection coverage, we gained access to the 3D architecture of the entire caldera fill. We also targeted the question of why the northern basin is 100 m deeper than the southern one. Finally, we tested whether Unit S3 consisted of flood debris from the caldera flooding event (Nomikou et al., 2016) or was Late Bronze Age intracaldera tuff (Johnston et al., 2015). The intracaldera sites were used for microbiological work of scientific Objective 7.