We present a comparative study of the tribological properties of Pd-, Pt-, and Zr-based bulk metallic glasses (BMG-Pd, BMG-Pt, and BMG-Zr, respectively) under unlubricated conditions. In particular, micro-tribometry is utilized with a 52,100 steel ball, showing that BMG-Pt exhibits a significantly higher coefficient of friction (COF) (0.58 ± 0.08) when compared with BMG-Pd (0.30 ± 0.02) and BMG-Zr (0.20 ± 0.03). Topographical roughness on and off wear scars is characterized via atomic force microscopy (AFM), with results that do not correlate with the observed frictional behavior. On the other hand, scanning electron microscopy (SEM) is utilized to reveal contrasting wear mechanisms for the three samples: while BMG-Pd and BMG-Zr exhibit predominantly abrasive wear, there is evidence of adhesive wear on BMG-Pt. Consequently, the occurrence of adhesive wear emerges as a potential mechanism behind the observation of relatively high coefficients of friction on BMG-Pt, suggesting stronger interactions with steel when compared with the other BMG samples.
more »
« less
Friction and Wear of Pd-Rich Amorphous Alloy (Pd43Cu27Ni10P20) with Ionic Liquid (IL) as Lubricant at High Temperatures
The friction and wear behavior of palladium (Pd)-rich amorphous alloy (Pd43Cu27Ni10P20) against 440C stainless steel under ionic liquids as lubricants, i.e., 1-nonyl-3-methylimidazolium bis[(trifluoromethane)sulfonyl]amide ([C9C1im][NTf2]), were investigated using a ball-on-disc reciprocating tribometer at ambient, 100 and 200 °C with different sliding speeds of 3 and 7 mm/s, whose results were compared to those from crystalline Pd samples. The measured coefficient of friction (COF) and wear were affected by both temperature and sliding speed. The COF of crystalline Pd samples dramatically increased when the temperature increased, whereas the COF of the amorphous Pd alloy samples remained low. As the sliding speed increased, the COF of both Pd samples showed decreasing trends. From the analysis of a 3D surface profilometer and scanning electron microscopy (SEM) with electron dispersive spectroscopy (EDS) data, three types of wear (i.e., delamination, adhesive, and abrasive wear) were observed on the crystalline Pd surfaces, whereas the amorphous Pd alloy surfaces produced abrasive wear only. In addition, X-ray photoelectron spectroscopy (XPS) measurements were performed to study the formation of tribofilm. It was found that the chemical reactivity at the contacting interface increased with temperature and sliding contact speed. The ionic liquids (ILs) were effective as lubricants when the applied temperature and sliding speed were 200 °C and 7 mm/s, respectively.
more »
« less
- NSF-PAR ID:
- 10155424
- Date Published:
- Journal Name:
- Metals
- Volume:
- 9
- Issue:
- 11
- ISSN:
- 2075-4701
- Page Range / eLocation ID:
- 1180
- Format(s):
- Medium: X
- Sponsoring Org:
- National Science Foundation
More Like this
-
-
null (Ed.)Here, we report the high-temperature superlubricity phenomenon accomplished in coatings produced by burnishing powders of antimony trioxide (Sb 2 O 3 ) and magnesium silicate hydroxide coated with carbon (MSH/C) onto the nickel superalloy substrate. The tribological analysis performed in an open-air experimental setup revealed that with the increase of testing temperature, the coefficient of friction (COF) of the coating gradually decreases, finally reaching the superlubricity regime (the COF of 0.008) at 300°C. The analysis of worn surfaces using in-situ Raman spectroscopy suggested the synergistic effect of the inner Sb 2 O 3 adhesion layer and the top MSH/C layer, which do not only isolate the substrate from the direct exposure to sliding but also protect it from oxidation. The cross-sectional transmission electron microscopy (TEM) and X-ray photoelectron spectroscopy (XPS) results indicated the tribochemically-activated formation of an amorphous carbon layer on the surface of the coating during sliding. Formation of the film enables the high-temperature macroscale superlubricity behavior of the material system.more » « less
-
more » « less
Abstract Flash‐weakening models typically show good agreement with the total magnitude of weakening in high‐speed rock friction experiments, however deviations during the acceleration and deceleration phases, and at low and intermediate sliding velocities, remain unresolved. Here, we incorporate inhomogeneous mm‐scale normal stress evolution into a model for flash heating and weakening to resolve outstanding transient and hysteretic friction observed in laboratory experiments and to identify unique solutions to constitutive parameters. We conduced 37 rock friction experiments on Westerly granite using a high‐speed biaxial apparatus outfitted with a high‐speed infrared camera. We initiated velocity steps from quasi‐static rates of 1 mm/s to sliding velocities ranging from 300 to 900 mm/s and conducted both constant‐ and decreasing‐velocity tests following the velocity step. Two sliding surfaces geometries were used to control mm‐scale life‐times and rest‐times. Constant‐strength sliding is achieved within 2–3 mm of initiating the velocity step in all constant‐velocity experiments. Macroscopic surface temperature is inhomogeneous and increases with slip distance, velocity, and decreasing rest‐time. Weakening increases with sliding velocity and decreasing rest‐time. We combine thermal models with measured surface temperatures to constrain the evolution of local normal stress at the mm‐scale and incorporate this evolution into a flash‐weakening model that considers weakening at both the µm‐ and mm‐scale. The flash‐weakening model improves when the effects of mm‐scale wear processes are incorporated and multi‐scale weakening is considered, however some transient friction remains undescribed. Models will be advanced by further incorporating wear processes and by considering processes at the mm‐scale and above.
-
Abstract Minimizing the wear of the surfaces exposed to mechanical shear stresses is a critical challenge for maximizing the lifespan of rotary mechanical parts. In this study, we have discovered the anti-wear capability of a series of metal nitride-copper nanocomposite coatings tested in a liquid hydrocarbon environment. The results indicate substantial reduction of the wear in comparison to the uncoated steel substrate. Analysis of the wear tracks indicates the formation of carbon-based protective films directly at the sliding interface during the tribological tests. Raman spectroscopy mapping of the wear track suggests the amorphous carbon (a-C) nature of the formed tribofilm. Further analysis of the tribocatalytic activity of the best coating candidate, MoN-Cu, as a function of load (0.25–1 N) and temperature (25 °C and 50 °C) was performed in three alkane solutions, decane, dodecane, and hexadecane. Results indicated that elevated temperature and high contact pressure lead to different tribological characteristics of the coating tested in different environments. The elemental energy dispersive x-ray spectroscopy analysis and Raman analysis revealed formation of the amorphous carbon film that facilitates easy shearing at the contact interface thus enabling more stable friction behavior and lower wear of the tribocatalytic coating. These findings provide new insights into the tribocatalysis mechanism that enables the formation of zero-wear coatings.more » « less
-
more » « less
Abstract Development of solid lubricant materials that render reliable performance in ambient conditions, are amenable to industrial size and design complexities, and work on engineered surfaces is reported. These coatings are composed of Ti3C2T
x -Graphene Oxide blends, spray-coated onto bearing steel surfaces. The tribological assessment was carried out in ambient environmental conditions and high contact pressures in a ball-on-disc experimental set-up. The evaluation yielded that the use of Ti3C2Tx -Graphene-Oxide coatings led to substantial reduction in friction down to 0.065 (at 1 GPa contact pressure and 100 mm/s) in comparison to the uncoated of single-component-coated surfaces, surpassing the state-of-the-art. The coatings also provided excellent protection against wear loss of the substrate and counter-face. The results were explained based on the observations from Raman spectroscopy, scanning electron microscopy, transmission electron microscopy, and nanoindentation measurements.In operando formation of a dense, hard and stiff, dangling-bond-saturated tribolayer was observed to be the reason for the sustained lubricity even at high test loads and sliding speeds. This report presents the holistic exploration and correlation of structure-property-processing pertaining to the advancement of solid lubrication science.
- Free Publicly Accessible Full Text
-
Accepted Manuscript1.0
- Journal Article:
- https://doi.org/10.3390/met9111180
