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1. Josephson Detection of Time Reversal Symmetry Breaking s +/- is Superconductivity in SnTe Nanowires

   Trimble, C.; Wei, M. T.; Kalantre, S. S.; Yuan, N. F.; Liu, P.; Cha, J. J.; Fu, L.; Williams, J. R. (January 2019, ArXiv.org)

   Exotic superconductivity, such as high TC, topological, and heavy-fermion superconductors, often rely on phase sensitive measurements to determine the underlying pairing. Here we investigate the proximity-induced superconductivity in nanowires of SnTe, where a s±is′ superconducting state is produced that lacks the time-reversal and valley-exchange symmetry of the parent SnTe. A systematic breakdown of three conventional characteristics of Josephson junctions -- the DC Josephson effect, the AC Josephson effect, and the magnetic diffraction pattern -- fabricated from SnTe nanowire weak links elucidates this novel superconducting state. Further, the AC Josephson effect reveals evidence of a Majorana bound state, tuned by a perpendicular magnetic field. This work represents the definitive phase-sensitive measurement of novel s±is′ superconductivity, providing a new route to the investigation of fractional vortices, topological superconductivity, topological phase transitions, and new types of Josephson-based devices. 

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2. Critical charge fluctuations and emergent coherence in a strongly correlated excitonic insulator

   https://doi.org/10.1038/s41535-021-00351-4  

   Volkov, P. A.; Ye, Mai; Lohani, H.; Feldman, I.; Kanigel, A.; Blumberg, G. (May 2021, npj Quantum Materials)

   Abstract Excitonic insulator is a coherent electronic phase that results from the formation of a macroscopic population of bound particle-hole pairs—excitons. With only a few candidate materials known, the collective excitonic behavior is challenging to observe, being obscured by crystalline lattice effects. Here we use polarization-resolved Raman spectroscopy to reveal the quadrupolar excitonic mode in the candidate zero-gap semiconductor Ta₂NiSe₅disentangling it from the lattice phonons. The excitonic mode pronouncedly softens close to the phase transition, showing its electronic character, while its coupling to noncritical lattice modes is shown to enhance the transition temperature. On cooling, we observe the gradual emergence of coherent superpositions of band states at the correlated insulator gap edge, with strong departures from mean-field theory predictions. Our results demonstrate the realization of a strongly correlated excitonic state in an equilibrium bulk material. 

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3. Superconductivity in the Parent Infinite-Layer Nickelate ${\mathrm{NdNiO}}_2$

   https://doi.org/10.1103/PhysRevX.15.021048  

   Parzyck, C T; Wu, Y; Bhatt, L; Kang, M; Arthur, Z; Pedersen, T M; Sutarto, R; Fan, S; Pelliciari, J; Bisogni, V; et al (May 2025, Physical Review X)

   We report evidence for superconductivity with onset temperatures up to 11 K in thin films of the infinite-layer nickelate parent compound ${\mathrm{NdNiO}}_2$. A combination of oxide molecular beam epitaxy and atomic hydrogen reduction yields samples with high crystallinity and low residual resistivities, a substantial fraction of which exhibit superconducting transitions. We survey a large series of samples with a variety of techniques, including electrical transport, scanning transmission electron microscopy, x-ray absorption spectroscopy, and resonant inelastic x-ray scattering, to investigate the possible origins of superconductivity. We propose that superconductivity could be intrinsic to the undoped infinite-layer nickelates but suppressed by disorder due to a possibly sign-changing order parameter, a finding which would necessitate a reconsideration of the nickelate phase diagram. Another possible hypothesis is that the parent materials can be hole doped from randomly dispersed apical oxygen atoms, which would suggest an alternative pathway for achieving superconductivity. Published by the American Physical Society2025 

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4. Quantum coherence tomography of light-controlled superconductivity

   https://doi.org/10.1038/s41567-022-01827-1  

   Luo, L.; Mootz, M.; Kang, J. H.; Huang, C.; Eom, K.; Lee, J. W.; Vaswani, C.; Collantes, Y. G.; Hellstrom, E. E.; Perakis, I. E.; et al (December 2022, Nature Physics)

   Abstract The coupling between superconductors and oscillation cycles of light pulses, i.e., lightwave engineering, is an emerging control concept for superconducting quantum electronics. Although progress has been made towards terahertz-driven superconductivity and supercurrents, the interactions able to drive non-equilibrium pairing are still poorly understood, partially due to the lack of measurements of high-order correlation functions. In particular, the sensing of exotic collective modes that would uniquely characterize light-driven superconducting coherence, in a way analogous to the Meissner effect, is very challenging but much needed. Here we report the discovery of parametrically driven superconductivity by light-induced order-parameter collective oscillations in iron-based superconductors. The time-periodic relative phase dynamics between the coupled electron and hole bands drives the transition to a distinct parametric superconducting state out-of-equalibrium. This light-induced emergent coherence is characterized by a unique phase–amplitude collective mode with Floquet-like sidebands at twice the Higgs frequency. We measure non-perturbative, high-order correlations of this parametrically driven superconductivity by separating the terahertz-frequency multidimensional coherent spectra into pump–probe, Higgs mode and bi-Higgs frequency sideband peaks. We find that the higher-order bi-Higgs sidebands dominate above the critical field, which indicates the breakdown of susceptibility perturbative expansion in this parametric quantum matter. 

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5. Antiferromagnetic excitonic insulator state in Sr3Ir2O7

   https://doi.org/10.1038/s41467-022-28207-w  

   Mazzone, D. G.; Shen, Y.; Suwa, H.; Fabbris, G.; Yang, J.; Zhang, S. -S.; Miao, H.; Sears, J.; Jia, Ke; Shi, Y. G.; et al (February 2022, Nature Communications)

   Abstract Excitonic insulators are usually considered to form via the condensation of a soft charge mode of bound electron-hole pairs. This, however, presumes that the soft exciton is of spin-singlet character. Early theoretical considerations have also predicted a very distinct scenario, in which the condensation of magnetic excitons results in an antiferromagnetic excitonic insulator state. Here we report resonant inelastic x-ray scattering (RIXS) measurements of Sr₃Ir₂O₇. By isolating the longitudinal component of the spectra, we identify a magnetic mode that is well-defined at the magnetic and structural Brillouin zone centers, but which merges with the electronic continuum in between these high symmetry points and which decays upon heating concurrent with a decrease in the material’s resistivity. We show that a bilayer Hubbard model, in which electron-hole pairs are bound by exchange interactions, consistently explains all the electronic and magnetic properties of Sr₃Ir₂O₇indicating that this material is a realization of the long-predicted antiferromagnetic excitonic insulator phase. 

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