An emerging chalcogenide perovskite, CaZrSe3, holds promise for energy conversion applications given its notable optical and electrical properties. However, knowledge of its thermal properties is extremely important, e.g. for potential thermoelectric applications, and has not been previously reported in detail. In this work, we examine and explain the lattice thermal transport mechanisms in CaZrSe3using density functional theory and Boltzmann transport calculations. We find the mean relaxation time to be extremely short corroborating an enhanced phonon–phonon scattering that annihilates phonon modes, and lowers thermal conductivity. In addition, strong anharmonicity in the perovskite crystal represented by the Grüneisen parameter predictions, and low phonon number density for the acoustic modes, results in the lattice thermal conductivity to be limited to 1.17 W m−1 K−1. The average phonon mean free path in the bulk CaZrSe3sample (
The broad bandwidth and spectral efficiency of photonics has facilitated unparalleled speeds in long-distance lightwave communication. Yet efficient routing and control of photonic information without optical-to-electrical conversion remains an ongoing research challenge. Here, we demonstrate a practical approach for dynamically transforming the carrier frequencies of dense wavelength-division–multiplexed data. Combining phase modulators and pulse shapers into an all-optical frequency processor, we realize both cyclic channel hopping and 1-to-
- Award ID(s):
- 1839191
- Publication Date:
- NSF-PAR ID:
- 10164581
- Journal Name:
- Optics Express
- Volume:
- 28
- Issue:
- 14
- Page Range or eLocation-ID:
- Article No. 20379
- ISSN:
- 1094-4087; OPEXFF
- Publisher:
- Optical Society of America
- Sponsoring Org:
- National Science Foundation
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