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1. Recent Updates to the Gas-phase Chemical Reactions and Molecular Lines in CLOUDY: Their Effects on Millimeter and Submillimeter Molecular Line Predictions

   https://doi.org/10.3847/1538-4357/ac7789  

   Shaw, Gargi ; Ferland, G. J. ; Chatzikos, M. ( July 2022 , The Astrophysical Journal)

   Here, we present our current updates to the gas-phase chemical reaction rates and molecular lines in the spectral synthesis codecloudy, and its implications in spectroscopic modeling of various astrophysical environments. We include energy levels, and radiative and collisional rates for HF, CF⁺, HC₃N, ArH⁺, HCl, HCN, CN, CH, and CH₂. Simultaneously, we expand our molecular network involving these molecules. For this purpose, we have added 561 new reactions and have updated the existing 165 molecular reaction rates involving these molecules. As a result,cloudynow predicts all the lines arising from these nine molecules. In addition, we also update H₂–H₂collisional data up to rotational levelsJ= 31 forv= 0. We demonstrate spectroscopic simulations of these molecules for a few astrophysical environments. Our existing model for globules in the Crab Nebula successfully predicts the observed column density of ArH⁺. Our model predicts a detectable amount of HeH⁺, OH⁺, and CH⁺for the Crab Nebula. We also model the interstellar medium toward HD185418, W31C, and NGC 253, and our predictions match with most of the observed column densities within the observed error bars. Very often molecular lines trace various physical conditions. Hence, this update will be very supportive for spectroscopic modeling of various astrophysical environments, particularly involving submillimeter and mid-infrared observations using the Atacama Large Millimeter/submillimeter Array and the James Webb Space Telescope, respectively.

    

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2. Nucleosynthesis of "Light" Heavy Nuclei in Neutrino-driven Winds. Role of ( α,n ) reactions

   https://doi.org/10.1088/1742-6596/1668/1/012033  

   Pereira, J. ; Arcones, A. ; Bliss, J. ; Montes, F. ( January 2020 , ArXivorg)

   Neutrino-driven winds following core collapse supernovae have been proposed as a suitable site where the so-called light heavy elements (between Sr to Ag) can be synthetized. For moderately neutron-rich winds, ( α,n ) reactions play a critical role in the weak r process, becoming the main mechanism to drive nuclear matter towards heavier elements. In this paper we summarize the sensitivity of network-calculated abundances to the astrophysical conditions, and to uncertainties in the ( α,n ) reaction rates. A list of few ( α,n ) reactions were identified to dominate the uncertainty in the calculated elemental abundances. Measurements of these reactions will allow to identify the astrophysical conditions of the weak r process by comparing calculated/observed abundances in r-limited stars. 

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3. Prospects for Surrogate Neutron Capture Measurements with Radioactive Ion Beams and GODDESS

   https://doi.org/10.1007/978-3-030-58082-7  

   Jolie A. Cizewski, Andrew Ratkiewicz ( February 2021 , Compound-Nuclear Reactions, Springer Proceedings in Physics 254)

   null (Ed.)

   Neutron capture reactions are responsible for the synthesis of almost all of the elements heavier than iron through the slow s-process, that proceeds close to the line of stability, and the rapid r-process, with very neutron-rich waiting points. Uncertainties in (n,γ) rates in neutron rich nuclei, especially near closed neu- tron shells, can have significant impact [1] on the predictions of final abundances for different astrophysical scenarios for the r process. Understanding (n,γ) rates on neutron-rich fission fragments is also important for nuclear forensics and stockpile stewardship science. Ratkiewicz et al. [2 and references therein] has recently demonstrated that the (d,pγ) reaction is a valid surrogate for (n,γ), where the formation of the compound nu- cleus from the breakup of the deuteron has been calculated in a reaction model and the subsequent measured gamma-decay probabilities are reproduced with standard level density and strength functions in a Bayesian approach. In parallel to the surrogate validation efforts, we have demonstrated that the (d,pγ) reaction can be measured in inverse kinematics with Gammasphere ORRUBA: Dual Detectors for Experimental Structure Studies (GODDESS) [3] where the Gammasphere array of Compton-suppressed HPGe detectors is coupled to the Oak Ridge Rutgers University Barrel Array of position-sensitive silicon strip detectors. During the commis- sioning campaign we measured the (d,pγ) reaction with 134Xe and 95Mo beams, the latter to demonstrate the surrogate method in inverse kinematics. The present talk will present preliminary results from this campaign including γ-decay probabilities and prospects for surrogate (n,γ) measurements with 143Ba fission-fragment beams. 

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4. Constraining Nucleosynthesis in Neutrino-driven Winds: Observations, Simulations, and Nuclear Physics

   https://doi.org/10.3847/1538-4357/ac7da7  

   Psaltis, A. ; Arcones, A. ; Montes, F. ; Mohr, P. ; Hansen, C. J. ; Jacobi, M. ; Schatz, H. ( August 2022 , The Astrophysical Journal)

   Abstract A promising astrophysical site to produce the lighter heavy elements of the first r -process peak ( Z = 38 − 47) is the moderately neutron-rich (0.4 < Y e < 0.5) neutrino-driven ejecta of explosive environments, such as core-collapse supernovae and neutron star mergers, where the weak r -process operates. This nucleosynthesis exhibits uncertainties from the absence of experimental data from ( α , xn ) reactions on neutron-rich nuclei, which are currently based on statistical model estimates. In this work, we report on a new study of the nuclear reaction impact using a Monte Carlo approach and improved ( α , xn ) rates based on the Atomki-V2 α optical model potential. We compare our results with observations from an up-to-date list of metal-poor stars with [Fe/H] < −1.5 to find conditions of the neutrino-driven wind where the lighter heavy elements can be synthesized. We identified a list of ( α , xn ) reaction rates that affect key elemental ratios in different astrophysical conditions. Our study aims to motivate more nuclear physics experiments on ( α , xn ) reactions using the current and new generation of radioactive beam facilities and also more observational studies of metal-poor stars. 

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5. Cascade Processes with Micellar Reaction Media: Recent Advances and Future Directions

   https://doi.org/10.3390/molecules27175611  

   Tang, Christina ; McInnes, Bridget T. ( September 2022 , Molecules)

   Reducing the use of solvents is an important aim of green chemistry. Using micelles self-assembled from amphiphilic molecules dispersed in water (considered a green solvent) has facilitated reactions of organic compounds. When performing reactions in micelles, the hydrophobic effect can considerably accelerate apparent reaction rates, as well as enhance selectivity. Here, we review micellar reaction media and their potential role in sustainable chemical production. The focus of this review is applications of engineered amphiphilic systems for reactions (surface-active ionic liquids, designer surfactants, and block copolymers) as reaction media. Micelles are a versatile platform for performing a large array of organic chemistries using water as the bulk solvent. Building on this foundation, synthetic sequences combining several reaction steps in one pot have been developed. Telescoping multiple reactions can reduce solvent waste by limiting the volume of solvents, as well as eliminating purification processes. Thus, in particular, we review recent advances in “one-pot” multistep reactions achieved using micellar reaction media with potential applications in medicinal chemistry and agrochemistry. Photocatalyzed reactions in micellar reaction media are also discussed. In addition to the use of micelles, we emphasize the process (steps to isolate the product and reuse the catalyst). 

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