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Title: Evidence for a lowest energy 3 MLCT excited state in [Fe(tpy)(CN) 3 ] −
Transient absorption data of [Fe II (tpy)(CN) 3 ] − reveals spectroscopic signatures indicative of 3 MLCT with a ∼10 ps kinetic component. These data are supported by DFT and TD-DFT calculations, which show that excited state ordering is responsive to the number of cyanide ligands on the complex.  more » « less
Award ID(s):
1856492 1920229
NSF-PAR ID:
10288994
Author(s) / Creator(s):
; ; ; ; ;
Date Published:
Journal Name:
Chemical Communications
Volume:
57
Issue:
38
ISSN:
1359-7345
Page Range / eLocation ID:
4658 to 4661
Format(s):
Medium: X
Sponsoring Org:
National Science Foundation
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