skip to main content
US FlagAn official website of the United States government
dot gov icon
Official websites use .gov
A .gov website belongs to an official government organization in the United States.
https lock icon
Secure .gov websites use HTTPS
A lock ( lock ) or https:// means you've safely connected to the .gov website. Share sensitive information only on official, secure websites.


Title: Structure and density of silicon carbide to 1.5 TPa and implications for extrasolar planets
Abstract There has been considerable recent interest in the high-pressure behavior of silicon carbide, a potential major constituent of carbon-rich exoplanets. In this work, the atomic-level structure of SiC was determined through in situ X-ray diffraction under laser-driven ramp compression up to 1.5 TPa; stresses more than seven times greater than previous static and shock data. Here we show that the B1-type structure persists over this stress range and we have constrained its equation of state (EOS). Using this data we have determined the first experimentally based mass-radius curves for a hypothetical pure SiC planet. Interior structure models are constructed for planets consisting of a SiC-rich mantle and iron-rich core. Carbide planets are found to be ~10% less dense than corresponding terrestrial planets.  more » « less
Award ID(s):
2020249
PAR ID:
10332399
Author(s) / Creator(s):
; ; ; ; ; ; ; ; ; ; ; ;
Date Published:
Journal Name:
Nature Communications
Volume:
13
Issue:
1
ISSN:
2041-1723
Format(s):
Medium: X
Sponsoring Org:
National Science Foundation
More Like this
  1. Rovibrational spectral data for several tetra-atomic silicon carbide clusters (TASCCs) are computed in this work using a CCSD(T)-F12b/cc-pCVTZ-F12 quartic force field. Accurate theoretical spectroscopic data may facilitate the observation of TASCCs in the interstellar medium which may lead to a more complete understanding of how the smallest silicon carbide (SiC) solids are formed. Such processes are essential for understanding SiC dust grain formation. Due to SiC dust prevalence in the interstellar medium, this may also shed light on subsequent planetary formation. Rhomboidal Si2C2is shown here to have a notably intense (247 km mol−1) anharmonic vibrational frequency at 988.1 cm−1(10.1 μm) forν2, falling into one of the spectral emission features typically associated with unknown infrared bands of various astronomical regions. Notable intensities are also present for several of the computed anharmonic vibrational frequencies including the cyclic forms of C4, SiC3, Si3C, and Si4. These features in the 6–10 μm range are natural targets for infrared observation with theJames Webb Space Telescope(JWST)’s MIRI instrument. Additionally,t-Si2C2,d-Si3C, andr-SiC3each possess dipole moments of greater than 2.0 D making them interesting targets for radioastronomical searches especially sinced-SiC3is already known in astrophysical media. 
    more » « less
  2. ABSTRACT The detection of the 11.3$$\, {\rm \mu m}$$ emission feature characteristic of the Si–C stretch in carbon-rich evolved stars reveals that silicon carbide (SiC) dust grains are condensed in the outflows of carbon stars. SiC dust could be a significant constituent of interstellar dust since it is generally believed that carbon stars inject a considerable amount of dust into the interstellar medium (ISM). The presence of SiC dust in the ISM is also supported by the identification of pre-solar SiC grains of stellar origin in primitive meteorites. However, the 11.3$$\,\mu {\rm m}$$ absorption feature of SiC has never been seen in the ISM, and oxidative destruction of SiC is often invoked. In this work, we quantitatively explore the destruction of interstellar SiC dust through oxidation based on molecular dynamics simulations and density functional theory calculations. We find that the reaction of an oxygen atom with SiC molecules and clusters is exothermic and could cause CO-loss. Nevertheless, even if this is extrapolable to bulk SiC dust, the destruction rate of SiC dust through oxidation could still be considerably smaller than the (currently believed) injection rate from carbon stars. Therefore, the lack of the 11.3$$\,\mu{\rm m}$$ absorption feature of SiC dust in the ISM remains a mystery. A possible solution may lie in the currently believed stellar injection rate of SiC (which may have been overestimated) and/or the size of SiC dust (which may actually be considerably smaller than submicron in size). 
    more » « less
  3. Abstract From transmission electron microscopy and other laboratory studies of presolar grains, the implicit condensation sequence of carbon-bearing condensates in circumstellar envelopes of carbon stars is (from first to last) TiC-graphite-SiC. We use thermochemical equilibrium condensation calculations and show that the condensation sequence of titanium carbide (TiC), graphite (C(Gr)), and silicon carbide (SiC) depends on metallicity in addition to C/O ratio and total pressure. Calculations were performed for a characteristic carbon star ratio of C/O = 1.2 from 10−10to 10−4bars total pressure and for uniform metallicity variations ranging from 0.01 to 100 times solar elemental abundances. TiC always condenses at higher temperatures than SiC, and the carbide condensation temperatures increase with both increasing metallicity and increasing total pressure. Graphite, however, can condense in a cooling circumstellar envelope before TiC, between TiC and SiC, or after SiC, depending on the carbon-bearing gas chemistry, which is dependent on metallicity and total pressure. Analytical expressions for the graphite, TiC, and SiC condensation temperatures as functions of metallicity and total pressure are presented. The inferred sequence from laboratory presolar grain studies, TiC-graphite-SiC, is favored under equilibrium conditions at solar and subsolar metallicities between ∼10−5and 10−8bar total pressure within circumstellar envelopes of carbon stars with nominal C/O = 1.2. We also explored the dependence of the sequence at C/O ratios of 1.1 and 3.0, and found that as the C/O ratio increases, the TiC-graphite-SiC condensation sequence region occurs toward higher total pressures and lower metallicities. 
    more » « less
  4. ABSTRACT Certain types of silicon carbide (SiC) grains, e.g. SiC-X grains, and low density (LD) graphites are C-rich presolar grains that are thought to have condensed in the ejecta of core-collapse supernovae (CCSNe). In this work, we compare C, N, Al, Si, and Ti isotopic abundances measured in presolar grains with the predictions of 21 CCSN models. The impact of a range of SN explosion energies is considered, with the high energy models favouring the formation of a C/Si zone enriched in 12C, 28Si, and 44Ti. Eighteen of the 21 models have H ingested into the He-shell and different abundances of H remaining from such H-ingestion. CCSN models with intermediate to low energy (that do not develop a C/Si zone) cannot reproduce the 28Si and 44Ti isotopic abundances in grains without assuming mixing with O-rich CCSN ejecta. The most 28Si-rich grains are reproduced by energetic models when material from the C/Si zone is mixed with surrounding C-rich material, and the observed trends of the 44Ti/48Ti and 49Ti/48Ti ratios are consistent with the C-rich C/Si zone. For the models with H-ingestion, high and intermediate explosion energies allow the production of enough 26Al to reproduce the 26Al/27Al measurements of most SiC-X and LD graphites. In both cases, the highest 26Al/27Al ratio is obtained with H still present at XH ≈ 0.0024 in He-shell material when the SN shock is passing. The existence of H in the former convective He-shell points to late H-ingestion events in the last days before massive stars explode as a supernova. 
    more » « less
  5. Silicon carbide (SiC) supports surface phonons in the infrared region of the electromagnetic spectrum where these modes can be thermally emitted. Additionally, the magnitude, spectrum, and direction of thermal radiation from SiC can be controlled by engineering this material at the sub-wavelength scale. For these reasons, SiC nanopillars are of high interest for thermal-radiation tuning. So far, theoretical and experimental studies of thermal emission from SiC nanopillars have been limited to long-pitch arrays with a microscale interpillar spacing. It is not clear how far-field thermal emission from SiC nanopillars is affected when the interparticle spacing reduces to the nanometer scale, where the near-field interaction between adjacent nanopillars arises and the array becomes zero order. In this Letter, we study physical mechanisms of far-field thermal radiation from zero-order arrays of silicon-carbide nanopillars with a nanoscale interpillar spacing. We show that the increased volume of thermal emitters and thermal radiation of the hybrid waveguide-surface-phonon-polariton mode from zero-order arrays increase the spectral emissivity of silicon carbide to values as large as 1 for a wide range of angles. The enhanced, dispersion-less thermal emission from a zero-order SiC array of nano-frustums with an optimized interspacing of 300 nm is experimentally demonstrated. Our study provides insight into thermal radiation from dense nanostructures and has significant implications for thermal management of electronic devices and energy harvesting applications. 
    more » « less