skip to main content
US FlagAn official website of the United States government
dot gov icon
Official websites use .gov
A .gov website belongs to an official government organization in the United States.
https lock icon
Secure .gov websites use HTTPS
A lock ( lock ) or https:// means you've safely connected to the .gov website. Share sensitive information only on official, secure websites.


Title: N-Heterocyclic Carbene-Photocatalyzed Tricomponent Regioselective 1,2-Diacylation of Alkenes Illuminates the Mechanistic Details of the Electron Donor–Acceptor Complex-Mediated Radical Relay Processes
Award ID(s):
1920057
PAR ID:
10341885
Author(s) / Creator(s):
; ; ; ; ; ;
Date Published:
Journal Name:
ACS Catalysis
Volume:
12
Issue:
1
ISSN:
2155-5435
Page Range / eLocation ID:
285 to 294
Format(s):
Medium: X
Sponsoring Org:
National Science Foundation
More Like this
  1. A bstract We report the first measurement of the exclusive cross sections e + e − → $$ B\overline{B} $$ B B ¯ , e + e − → $$ B{\overline{B}}^{\ast } $$ B B ¯ ∗ , and e + e − → $$ {B}^{\ast }{\overline{B}}^{\ast } $$ B ∗ B ¯ ∗ in the energy range from 10 . 63 GeV to 11 . 02 GeV. The B mesons are fully reconstructed in a large number of hadronic final states and the three channels are identified using a beam-constrained-mass variable. The shapes of the exclusive cross sections show oscillatory behavior with several maxima and minima. The results are obtained using data collected by the Belle experiment at the KEKB asymmetric-energy e + e − collider. 
    more » « less
  2. A<sc>bstract</sc> We report measurements of thee+e→$$ B\overline{B} $$ B B ¯ ,$$ B{\overline{B}}^{\ast } $$ B B ¯ , and$$ {B}^{\ast }{\overline{B}}^{\ast } $$ B B ¯ cross sections at four energies, 10653, 10701, 10746 and 10805 MeV, using data collected by the Belle II experiment. We reconstruct oneBmeson in a large number of hadronic final states and use its momentum to identify the production process. In the first 2 – 5 MeV above$$ {B}^{\ast }{\overline{B}}^{\ast } $$ B B ¯ threshold, thee+e→$$ {B}^{\ast }{\overline{B}}^{\ast } $$ B B ¯ cross section increases rapidly. This may indicate the presence of a pole close to the threshold. 
    more » « less
  3. null (Ed.)
    Abstract We show that for some even $$k\leqslant 3570$$ and all  $$k$$ with $442720643463713815200|k$, the equation $$\phi (n)=\phi (n+k)$$ has infinitely many solutions $$n$$, where $$\phi $$ is Euler’s totient function. We also show that for a positive proportion of all $$k$$, the equation $$\sigma (n)=\sigma (n+k)$$ has infinitely many solutions $$n$$. The proofs rely on recent progress on the prime $$k$$-tuples conjecture by Zhang, Maynard, Tao, and PolyMath. 
    more » « less
  4. Abstract The 2021MW6.0 Yangbi, Yunnan strike‐slip earthquake occurred on an unmapped crustal fault near the Weixi‐Qiaoho‐Weishan Fault along the southeast margin of the Tibetan Plateau. Using near‐source broadband seismic data from ChinArray, we investigate the spatial and temporal rupture evolution of the mainshock using apparent moment‐rate functions (AMRFs) determined by the empirical Green's function (EGF) method. Assuming a 1D line source on the fault plane, the rupture propagated unilaterally southeastward (∼144°) over a rupture length of ∼8.0 km with an estimated rupture speed of 2.1 km/s to 2.4 km/s. A 2D coseismic slip distribution for an assumed maximum rupture propagation speed of 2.2 km/s indicates that the rupture propagated to the southeast ∼8.0 km along strike and ∼5.0 km downdip with a peak slip of ∼2.1 m before stopping near the largest foreshock, where three bifurcating subfaults intersect. Using the AMRFs, the radiated energy of the mainshock is estimated as ∼. The relatively low moment scaled radiated energyof 1.5 × 10−5and intense foreshock and aftershock activity might indicate reactivation of an immature fault. The earthquake sequence is mainly distributed along a northwest‐southeast trend, and aftershocks and foreshocks are distributed near the periphery of the mainshock large‐slip area, suggesting that the stress in the mainshock slip zone is significantly reduced to below the level for more than a few overlapping aftershock to occur. 
    more » « less