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Title: Mid-IR spectroscopy of Er 3+ doped low-phonon CsCdCl 3 and CsPbCl 3 crystals

The mid-IR spectroscopic properties ofEr3+doped low-phononCsCdCl3andCsPbCl3crystals grown by the Bridgman technique have been investigated. Using optical excitations at∼<#comment/>800nmand∼<#comment/>660nm, both crystals exhibited IR emissions at∼<#comment/>1.55,∼<#comment/>2.75,∼<#comment/>3.5, and∼<#comment/>4.5µ<#comment/>mat room temperature. The mid-IR emission at 4.5 µm, originating from the4I9/2→<#comment/>4I11/2transition, showed a long emission lifetime of∼<#comment/>11.6msforEr3+dopedCsCdCl3, whereasEr3+dopedCsPbCl3exhibited a shorter lifetime of∼<#comment/>1.8ms. The measured emission lifetimes of the4I9/2state were nearly independent of the temperature, indicating a negligibly small nonradiative decay rate through multiphonon relaxation, as predicted by the energy-gap law for low-maximum-phonon energy hosts. The room temperature stimulated more » emission cross sections for the4I9/2→<#comment/>4I11/2transition inEr3+dopedCsCdCl3andCsPbCl3were determined to be∼<#comment/>0.14×<#comment/>10−<#comment/>20cm2and∼<#comment/>0.41×<#comment/>10−<#comment/>20cm2, respectively. The results of Judd–Ofelt analysis are presented and discussed.

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Authors:
; ; ; ; ; ; ;
Publication Date:
NSF-PAR ID:
10372091
Journal Name:
Journal of the Optical Society of America B
Volume:
40
Issue:
1
Page Range or eLocation-ID:
Article No. A1
ISSN:
0740-3224; JOBPDE
Publisher:
Optical Society of America
Sponsoring Org:
National Science Foundation
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