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1. Mobility of Magmas Within the Earth: Insights From the Elasticity and Transport Properties of Hydrous Albitic Melts

   https://doi.org/10.1029/2024GC011510  

   Ashley, Aaron_Wolfgang; Bajgain, Suraj; Mookherjee, Mainak (June 2024, Geochemistry, Geophysics, Geosystems)

   Abstract The continental crust is produced by the solidification of aluminosilicate‐rich magmas which are sourced from deep below the surface. Migration of the magma depends on the density (ρ) contrast to source rocks and the melt viscosity (η). At the surface, these silica‐rich melts are typically sluggish due to highη > 1,000 Pa s. Yet at their source regions, the melt properties are complexly influenced by pressure (P), temperature (T), and water contents (). In this study, we examined the combinedP‐T‐ effects on the behavior of melts with an albite stoichiometry (NaAlSi₃O₈). We usedfirst‐principlesmolecular dynamics simulations to examine anhydrous (0 wt % H₂O) and hydrous (5 wt % H₂O) melts. To constrain thePandTeffects, we exploredP ≤ 25 GPa across several isotherms between 2500 and 4000 K. The melts show anomalousP‐ρrelationships at lowP ∼ 0 GPa and highT ≥ 2500 K, consistent with vaporization. At lithospheric conditions, meltρincreases with compression and is well described by a finite‐strain formalism. Water lowers the melt density (ρ_hydrous < ρ_anhydrous) but increases the compressibility, that is, 1/K_hydrous>1/K_anhydrousorK_hydrous < K_anhydrous. We also find that the meltηdecreases with pressure and then increases with further compression. Water decreases the viscosity (η_hydrous < η_anhydrous) by depolymerizing the melt structure. The ionic self‐diffusivities are increased by the presence of water. The decreasedρandηby H₂O increase the mobility of magma at crustal conditions, which could explain the rapid eruption and migration timescales for rhyolitic magmas as observed in the Chaitén volcano in Chile. 

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2. Scaling Analysis of Shear Thickening Suspensions

   https://doi.org/10.3389/fphy.2022.946221  

   Malbranche, Nelya; Santra, Aritra; Chakraborty, Bulbul; Morris, Jeffrey F. (July 2022, Frontiers in Physics)

   Dense suspensions of particles in viscous liquid often demonstrate the striking phenomenon of abrupt shear thickening, where their viscosity increases strongly with increase of the imposed stress or shear rate. In this work, discrete-particle simulations accounting for short-range hydrodynamic, repulsive, and contact forces are performed to simulate flow of shear thickening bidisperse suspensions, with the packing parameters of large-to-small particle radius ratio δ = 3 and large particle fraction ζ = 0.15, 0.50, and 0.85. The simulations are carried out for volume fractions 0.54 ≤ ϕ ≤ 0.60 and a wide range of shear stresses. The repulsive forces, of magnitude F R , model the effects of surface charge and electric double-layer overlap, and result in shear thinning at small stress, with shear thickening beginning at stresses σ ∼ F R a −2 . A crossover scaling analysis used to describe systems with more than one thermodynamic critical point has recently been shown to successfully describe the experimentally-observed shear thickening behavior in suspensions. The scaling theory is tested here on simulated shear thickening data of the bidisperse mixtures, and also on nearly monodisperse suspensions with δ = 1.4 and ζ = 0.50. Presenting the viscosity in terms of a universal crossover scaling function between the frictionless and frictional maximum packing fractions collapses the viscosity for most of the suspensions studied. Two scaling regimes having different exponents are observed. The scaling analysis shows that the second normal stress difference N 2 and the particle pressure Π also collapse on their respective curves, with the latter featuring a different exponent from the viscosity and normal stress difference. The influence of the fraction of frictional contacts, one of the parameters of the scaling analysis, and its dependence on the packing parameters are also presented. 

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3. 3D Printing of Microgel Scaffolds with Tunable Void Fraction to Promote Cell Infiltration

   https://doi.org/10.1002/adhm.202100644  

   Seymour, Alexis_J; Shin, Sungchul; Heilshorn, Sarah_C (August 2021, Advanced Healthcare Materials)

   Abstract Granular, microgel‐based materials have garnered interest as promising tissue engineering scaffolds due to their inherent porosity, which can promote cell infiltration. Adapting these materials for 3D bioprinting, while maintaining sufficient void space to enable cell migration, can be challenging, since the rheological properties that determine printability are strongly influenced by microgel packing and void fraction. In this work, a strategy is proposed to decouple printability and void fraction by blending UV‐crosslinkable gelatin methacryloyl (GelMA) microgels with sacrificial gelatin microgels to form composite inks. It is observed that inks with an apparent viscosity greater than ≈100 Pa s (corresponding to microgel concentrations ≥5 wt%) have rheological properties that enable extrusion‐based printing of multilayered structures in air. By altering the ratio of GelMA to sacrificial gelatin microgels, while holding total concentration constant at 6 wt%, a family of GelMA:gelatin microgel inks is created that allows for tuning of void fraction from 0.20 to 0.57. Furthermore, human umbilical vein endothelial cells (HUVEC) seeded onto printed constructs are observed to migrate into granular inks in a void fraction‐dependent manner. Thus, the family of microgel inks holds promise for use in 3D printing and tissue engineering applications that rely upon cell infiltration. 

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4. Effect of polydispersity in concentrated magnetorheological fluids

   https://doi.org/10.1088/1361-665X/acbb47  

   Manuel, Júlio_Gabriel_de Falco; Bombard, Antonio_José Faria; Weeks, Eric R (March 2023, Smart Materials and Structures)

   Abstract Magnetorheological fluids (MRF) are smart materials of increasing interest due to their great versatility in mechanical and mechatronic systems. As main rheological features, MRFs must present low viscosity in the absence of magnetic field (0.1–1.0 Pa.s) and high yield stress (50–100 kPa) when magnetized, in order to optimize the magnetorheological effect. Such properties, in turn, are directly influenced by the composition, volume fraction, size, and size distribution (polydispersity) of the particles, the latter being an important piece in the improvement of these main properties. In this context, the present work aims to analyze, through experiments and simulations, the influence of polydispersity on the maximum packing fraction, on the yield stress under field (on-state) and on the plastic viscosity in the absence of field (off-state) of concentrated MRF (φ= 48.5 vol.%). Three blends of carbonyl iron powder (CIP) in polyalphaolefin oil were prepared. These blends have the same mode, but different polydispersity indexes (α), ranging from 0.46 to 1.44. Separate simulations show that the random close packing fraction increases from about 68% to 80% as the polydispersity indexes increase over this range. The on-state yield stress, in turn, is raised from 30 ± 0.5 kPa to 42 ± 2 kPa (B≈ 0.57 T) and the off-state plastic viscosity, is reduced from 4.8 Pa.s to 0.5 Pa.s. Widening the size distributions, as is well known in the literature, increases packing efficiency and reduces the viscosity of concentrated dispersions, but beyond that, it proved to be a viable way to increase the magnetorheological effect of concentrated MRF. The Brouwers model, which considers the void fraction in suspensions of particles with lognormal distribution, was proposed as a possible hypothesis to explain the increase in yield stress under magnetic field. 

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5. Analysis of modeled 3D solar magnetic field during 30 X/M-class solar flares

   https://doi.org/10.3389/fspas.2024.1369749  

   Garland, Seth H; Yurchyshyn, Vasyl B; Loper, Robert D; Akers, Benjamin F; Emmons, Daniel J (May 2024, Frontiers in Astronomy and Space Sciences)

   Using non-linear force free field (NLFFF) extrapolation, 3D magnetic fields were modeled from the 12-min cadence Solar Dynamics Observatory Helioseismic and Magnetic Imager (HMI) photospheric vector magnetograms, spanning a time period of 1 hour before through 1 hour after the start of 18 X-class and 12 M-class solar flares. Several magnetic field parameters were calculated from the modeled fields directly, as well as from the power spectrum of surface maps generated by summing the fields along the vertical axis, for two different regions: areas with photospheric |B_z|≥ 300 G (active region—AR) and areas above the photosphere with the magnitude of the non-potential field (B_NP) greater than three standard deviations above $\overline{\left|{\mathit{B}}_{\mathit{N}\mathit{P}}\right|}$of the AR field and either the unsigned twist number |T_w| ≥ 1 turn or the shear angle Ψ ≥ 80° (non-potential region—NPR). Superposed epoch (SPE) plots of the magnetic field parameters were analyzed to investigate the evolution of the 3D solar field during the solar flare events and discern consistent trends across all solar flare events in the dataset, as well as across subsets of flare events categorized by their magnetic and sunspot classifications. The relationship between different flare properties and the magnetic field parameters was quantitatively described by the Spearman ranking correlation coefficient, r_s. The parameters that showed the most consistent and discernable trends among the flare events, particularly for the hour leading up to the eruption, were the total unsigned fluxϕ), free magnetic energy (E_Free), total unsigned magnetic twist (τ_Tot), and total unsigned free magnetic twist (ρ_Tot). Strong (|r_s| ∈ [0.6, 0.8)) to very strong (|r_s| ∈ [0.8, 1.0]) correlations were found between the magnetic field parameters and the following flare properties: peak X-ray flux, duration, rise time, decay time, impulsiveness, and integrated flux; the strongest correlation coefficient calculated for each flare property was 0.62, 0.85, 0.73, 0.82, −0.81, and 0.82, respectively. 

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