Abstract The continental crust is produced by the solidification of aluminosilicate‐rich magmas which are sourced from deep below the surface. Migration of the magma depends on the density (ρ) contrast to source rocks and the melt viscosity (η). At the surface, these silica‐rich melts are typically sluggish due to highη > 1,000 Pa s. Yet at their source regions, the melt properties are complexly influenced by pressure (P), temperature (T), and water contents (). In this study, we examined the combinedP‐T‐ effects on the behavior of melts with an albite stoichiometry (NaAlSi3O8). We usedfirst‐principlesmolecular dynamics simulations to examine anhydrous (0 wt % H2O) and hydrous (5 wt % H2O) melts. To constrain thePandTeffects, we exploredP ≤ 25 GPa across several isotherms between 2500 and 4000 K. The melts show anomalousP‐ρrelationships at lowP ∼ 0 GPa and highT ≥ 2500 K, consistent with vaporization. At lithospheric conditions, meltρincreases with compression and is well described by a finite‐strain formalism. Water lowers the melt density (ρhydrous < ρanhydrous) but increases the compressibility, that is, 1/Khydrous>1/KanhydrousorKhydrous < Kanhydrous. We also find that the meltηdecreases with pressure and then increases with further compression. Water decreases the viscosity (ηhydrous < ηanhydrous) by depolymerizing the melt structure. The ionic self‐diffusivities are increased by the presence of water. The decreasedρandηby H2O increase the mobility of magma at crustal conditions, which could explain the rapid eruption and migration timescales for rhyolitic magmas as observed in the Chaitén volcano in Chile.
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Free volume theory explains the unusual behavior of viscosity in a non-confluent tissue during morphogenesis
A recent experiment on zebrafish blastoderm morphogenesis showed that the viscosity (η) of a non-confluent embryonic tissue grows sharply until a critical cell packing fraction (ϕS). The increase inηup toϕSis similar to the behavior observed in several glass-forming materials, which suggests that the cell dynamics is sluggish or glass-like. Surprisingly,ηis a constant aboveϕS. To determine the mechanism of this unusual dependence ofηonϕ, we performed extensive simulations using an agent-based model of a dense non-confluent two-dimensional tissue. We show that polydispersity in the cell size, and the propensity of the cells to deform, results in the saturation of the available free area per cell beyond a critical packing fraction. Saturation in the free space not only explains the viscosity plateau aboveϕSbut also provides a relationship between equilibrium geometrical packing to the dramatic increase in the relaxation dynamics.
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- Award ID(s):
- 2310639
- PAR ID:
- 10510205
- Publisher / Repository:
- eLife
- Date Published:
- Journal Name:
- eLife
- Volume:
- 12
- ISSN:
- 2050-084X
- Page Range / eLocation ID:
- RP87966
- Format(s):
- Medium: X
- Sponsoring Org:
- National Science Foundation
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