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1. Low-energy magnetic states of Tb adatom on graphene

   https://doi.org/10.1088/1361-648X/ad8fe9  

   Shaikh, Monirul; Klein, Alison; Wysocki, Aleksander L (November 2024, Journal of Physics: Condensed Matter)

   Abstract Electronic structure and magnetic interactions of a Tb adatom on graphene are investigated from first principles using combination of density functional theory and multiconfigurational quantum chemistry techniques including spin–orbit coupling (SOC) . We determine that the six-fold symmetry hollow site is the preferred adsorption site and investigate electronic spectrum for different adatom oxidation states including Tb³⁺, Tb²⁺, Tb¹⁺, and Tb⁰. For all charge states, the Tb $4f^8$configuration is retained with other adatom valence electrons being distributed over $5d_{xy}$, $5d_{x2+y2}$, and $6s/5d_0$single-electron orbitals. We find strong intra-site adatom exchange coupling that ensures that the $5d6s$spins are parallel to the4fspin. For Tb³⁺, the energy levels can be described by theJ = 6 multiplet split by the graphene crystal field (CF). For other oxidation states, the interaction of4felectrons with spin and orbital degrees of freedom of $6s5d$electrons in the presence of SOC results in the low-energy spectrum composed closely lying effective multiplets that are split by the graphene CF. Stable magnetic moment is predicted for Tb³⁺and Tb²⁺adatoms due to uniaxial magnetic anisotropy and effective anisotropy barrier around 440 cm⁻¹controlled by the temperature assisted quantum tunneling of magnetization through the third excited doublet. On the other hand, in-plane magnetic anisotropy is found for Tb¹⁺and Tb⁰adatoms. Our results indicate that the occupation of the $6s5d$orbitals can dramatically affect the magnetic anisotropy and magnetic moment stability of rare earth adatoms. 

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2. Spin stiffness and spin excitation gap of van der Waals ferromagnetic ${\mathrm{Fe}}_{3+\delta }{\mathrm{GeTe}}_2$

   https://doi.org/10.1088/1361-648X/ad581f  

   Shu, Zhixue; Zhang, Shufeng; Kong, Tai (June 2024, Journal of Physics: Condensed Matter)

   Abstract ${\mathrm{Fe}}_{3+\delta }{\mathrm{GeTe}}_2$(FGT) has proved to be an interesting van der Waals (vdW) ferromagnetic compound with a tunable Curie temperature ( $T_{\mathrm{C}}$). However, the underlying mechanism for varying $T_{\mathrm{C}}$remains elusive. Here, we systematically investigate and compare low-temperature magnetic properties of single crystalline FGT samples that exhibit $T_{\mathrm{C}}$s ranging from 160 K to 205 K. Spin stiffness (D) and spin excitation gap (Δ) are extracted using Bloch’s theory for crystals with varying Fe content. Compared to Cr-based vdW ferromagnets, FGT compounds have higher spin stiffness values but lower spin wave excitation gaps. We discuss the implication of these relationships in Fe–Fe ion magnetic interactions in FGT unit cells. The itinerancy of magnetic electrons is measured and discussed under the Rhodes–Wohlfarth ratio (RWR) and the Takahashi theory. 

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3. The metastable Q ³ Δ ₂ state of ThO: a new resource for the ACME electron EDM search

   https://doi.org/10.1088/1367-2630/ab6a3a  

   Wu, X.; Han, Z.; Chow, J.; Ang, D. G.; Meisenhelder, C.; Panda, C. D.; West, E. P.; Gabrielse, G.; Doyle, J. M.; DeMille, D. (February 2020, New Journal of Physics)

   Abstract The best upper limit for the electron electric dipole moment was recently set by the ACME collaboration. This experiment measures an electron spin-precession in a cold beam of ThO molecules in their metastable $H{(}^3{\mathrm{\Delta }}_1)$state. Improvement in the statistical and systematic uncertainties is possible with more efficient use of molecules from the source and better magnetometry in the experiment, respectively. Here, we report measurements of several relevant properties of the long-lived $Q{(}^3{\mathrm{\Delta }}_2)$state of ThO, and show that this state is a very useful resource for both these purposes. TheQstate lifetime is long enough that its decay during the time of flight in the ACME beam experiment is negligible. The large electric dipole moment measured for theQstate, giving rise to a large linear Stark shift, is ideal for an electrostatic lens that increases the fraction of molecules detected downstream. The measured magnetic moment of theQstate is also large enough to be used as a sensitive co-magnetometer in ACME. Finally, we show that theQstate has a large transition dipole moment to the $C{(}^1{\mathrm{\Pi }}_1)$state, which allows for efficient population transfer between the ground state $X{(}^1{\mathrm{\Sigma }}^{+})$and theQstate via $X-C-Q$Stimulated Raman Adiabatic Passage (STIRAP). We demonstrate 90 % STIRAP transfer efficiency. In the course of these measurements, we also determine the magnetic moment ofCstate, the $X\to C$transition dipole moment, and branching ratios of decays from theCstate. 

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4. An optical atomic clock using $4D_J$ states of rubidium

   https://doi.org/10.1088/2058-9565/ad77ef  

   Duspayev, A.; Owens, C.; Dash, B.; Raithel, G. (September 2024, Quantum Science and Technology)

   Abstract We analyze an optical atomic clock using two-photon $5S_{1/2}\to 4D_J$transitions in rubidium. Four one- and two-color excitation schemes to probe the $4D_{3/2}$and $4D_{5/2}$fine-structure states are considered in detail. We compare key characteristics of Rb $4D_J$and $5D_{5/2}$two-photon clocks. The $4D_J$clock features a high signal-to-noise ratio due to two-photon decay at favorable wavelengths, low dc electric and magnetic susceptibilities, and minimal black-body shifts. Ac Stark shifts from the clock interrogation lasers are compensated by two-color Rabi-frequency matching. We identify a ‘magic’ wavelength near 1060 nm, which allows for in-trap, Doppler-free clock-transition interrogation with lattice-trapped cold atoms. From our analysis of clock statistics and systematics, we project a quantum-noise-limited relative clock stability at the ${10}^{-13}/\sqrt{\tau \left(s\right)}$-level, with integration timeτin seconds, and a relative accuracy of $\sim {10}^{-13}$. We describe a potential architecture for implementing the proposed clock using a single telecom clock laser at 1550 nm, which is conducive to optical communication and long-distance clock comparisons. Our work could be of interest in efforts to realize small and portable Rb clocks and in high-precision measurements of atomic properties of Rb $4D_J$-states. 

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5. Stellar Metallicities and Gradients in the Isolated, Quenched Low-mass Galaxy Tucana

   https://doi.org/10.3847/1538-4357/ad25ed  

   Fu, Sal_Wanying; Weisz, Daniel_R; Starkenburg, Else; Martin, Nicolas; Mercado, Francisco_J; Savino, Alessandro; Boylan-Kolchin, Michael; Côté, Patrick; Dolphin, Andrew_E; Longeard, Nicolas; et al (April 2024, The Astrophysical Journal)

   Abstract We measure the metallicities of 374 red giant branch (RGB) stars in the isolated, quenched dwarf galaxy Tucana using Hubble Space Telescope narrowband (F395N) calcium H and K imaging. Our sample is a factor of ∼7 larger than what is available from previous studies. Our main findings are as follows. (i) A global metallicity distribution function (MDF) with $〈\mathrm{[Fe/H]}〉=-{1.55}_{-0.04}^{+0.04}$and ${\sigma }_{\mathrm{[Fe/H]}}={0.54}_{-0.03}^{+0.03}$. (ii) A metallicity gradient of −0.54 ± 0.07 dex $R_e^{-1}$(−2.1 ± 0.3 dex kpc⁻¹) over the extent of our imaging (∼2.5R_e), which is steeper than literature measurements. Our finding is consistent with predicted gradients from the publicly available FIRE-2 simulations, in which bursty star formation creates stellar population gradients and dark matter cores. (iii) Tucana’s bifurcated RGB has distinct metallicities: a blue RGB with $〈\mathrm{[Fe/H]}〉=-{1.78}_{-0.06}^{+0.06}$and ${\sigma }_{\mathrm{[Fe/H]}}={0.44}_{-0.06}^{+0.07}$and a red RGB with $〈\mathrm{[Fe/H]}〉=-{1.08}_{-0.07}^{+0.07}$and ${\sigma }_{\mathrm{[Fe/H]}}={0.42}_{-0.06}^{+0.06}$. (iv) At fixed stellar mass, Tucana is more metal-rich than Milky Way satellites by ∼0.4 dex, but its blue RGB is chemically comparable to the satellites. Tucana’s MDF appears consistent with star-forming isolated dwarfs, though MDFs of the latter are not as well populated. (v) About 2% of Tucana’s stars have [Fe/H] < −3% and 20% have [Fe/H] > −1. We provide a catalog for community spectroscopic follow-up. 

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