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  • Ultrasound-Assisted Photocatalytic Degradation of Azo Dyes under Visible Light Irradiation Using Polythiophene-Decorated CoFe2O4 Nanohybrids
Title: Ultrasound-Assisted Photocatalytic Degradation of Azo Dyes under Visible Light Irradiation Using Polythiophene-Decorated CoFe2O4 Nanohybrids
The present work reports the synthesis of cobalt ferrite and its nanohybrids with polythiophene (PTh) in the weight ratios of 10% and 20%. The ferrite and its nanohybrids were characterized using thermogravimetric analysis (TGA), X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS) and scanning electron microscopy coupled with elemental mapping (Fe-SEM) to confirm the morphology as well as the structure of the synthesized nanohybrids. The nanohybrids were tested for their photocatalytic activity upon modification of PTh against Alizarin Yellow (AY), Congo Red (CR) and Brilliant Blue (BB). Almost 100% degradation was achieved in 30 min using 50 mg of the photocatalyst. The effect of catalyst concentration and dye concentration was also investigated to explore optimum concentration of the photocatalyst required for rapid degradation of the dye. The generation of radicals responsible for degradation was analyzed by radical scavenging experiments and a probable mechanism of degradation was proposed.  more » « less
Award ID(s):
2122044
PAR ID:
10582780
Author(s) / Creator(s):
; ;
Publisher / Repository:
MDPI
Date Published:
Journal Name:
Catalysts
Volume:
14
Issue:
8
ISSN:
2073-4344
Page Range / eLocation ID:
495
Format(s):
Medium: X
Sponsoring Org:
National Science Foundation
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