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This content will become publicly available on November 1, 2025

Title: Pseudo-easy-axis anisotropy in antiferromagnetic S=1 diamond-lattice systems
We investigate the magnetic properties of S = 1 antiferromagnetic diamond-lattice, Ni X 2 ( pyrimidine ) 2 ( X = Cl ,   Br ) , hosting a single-ion anisotropy (SIA) orientation which alternates between neighboring sites. Through neutron diffraction measurements of the X = Cl compound, the ordered state spins are found to align collinearly along a pseudo-easy axis, a unique direction created by the intersection of two easy planes. Similarities in the magnetization, exhibiting spin-flop transitions, and the magnetic susceptibility in the two compounds imply that the same magnetic structure and a pseudo-easy axis is also present for X = Br . We estimate the Hamiltonian parameters by combining analytical calculations and Monte Carlo (MC) simulations of the spin-flop and saturation field. The MC simulations also reveal that the spin-flop transition occurs when the applied field is parallel to the pseudo-easy axis. Contrary to conventional easy-axis systems, there exist field directions perpendicular to the pseudo-easy axis for which the magnetic saturation is approached asymptotically and no symmetry-breaking phase transition is observed at finite fields. Published by the American Physical Society2024  more » « less
Award ID(s):
2104167
PAR ID:
10595432
Author(s) / Creator(s):
; ; ; ; ; ; ; ; ; ; ; ; ; ;
Publisher / Repository:
Physical Review B
Date Published:
Journal Name:
Physical Review B
Volume:
110
Issue:
17
ISSN:
2469-9950
Format(s):
Medium: X
Sponsoring Org:
National Science Foundation
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