Materials composed of spin-1 antiferromagnetic (AFM) chains are known to adopt complex ground states that are sensitive to the single-ion-anisotropy (SIA) energy ( ), and intrachain ( ) and interchain ( ) exchange energy scales. While theoretical and experimental studies have extended this model to include various other energy scales, the effect of the lack of a common SIA axis is not well explored. Here we investigate the magnetic properties of , a chain compound where the tilting of Ni octahedra leads to a twofold alternation of the easy-axis directions along the chain. Muon-spin relaxation measurements indicate a transition to long-range order at and the magnetic structure is initially determined to be antiferromagnetic and collinear using elastic neutron diffraction experiments. Inelastic neutron scattering measurements were used to find , and a rhombic anisotropy energy . Mean-field modeling reveals that the ground state structure hosts spin canting of , which is not detectable above the noise floor of the elastic neutron diffraction data. Monte Carlo simulation of the powder-averaged magnetization, , is then used to confirm these Hamiltonian parameters, while single-crystal simulations provide insight into features observed in the data. Published by the American Physical Society2025 
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                    This content will become publicly available on November 1, 2025
                            
                            Pseudo-easy-axis anisotropy in antiferromagnetic S=1 diamond-lattice systems
                        
                    
    
            We investigate the magnetic properties of antiferromagnetic diamond-lattice,  , hosting a single-ion anisotropy (SIA) orientation which alternates between neighboring sites. Through neutron diffraction measurements of the compound, the ordered state spins are found to align collinearly along a pseudo-easy axis, a unique direction created by the intersection of two easy planes. Similarities in the magnetization, exhibiting spin-flop transitions, and the magnetic susceptibility in the two compounds imply that the same magnetic structure and a pseudo-easy axis is also present for . We estimate the Hamiltonian parameters by combining analytical calculations and Monte Carlo (MC) simulations of the spin-flop and saturation field. The MC simulations also reveal that the spin-flop transition occurs when the applied field is parallel to the pseudo-easy axis. Contrary to conventional easy-axis systems, there exist field directions perpendicular to the pseudo-easy axis for which the magnetic saturation is approached asymptotically and no symmetry-breaking phase transition is observed at finite fields. Published by the American Physical Society2024 
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                            - Award ID(s):
- 2104167
- PAR ID:
- 10595432
- Publisher / Repository:
- Physical Review B
- Date Published:
- Journal Name:
- Physical Review B
- Volume:
- 110
- Issue:
- 17
- ISSN:
- 2469-9950
- Format(s):
- Medium: X
- Sponsoring Org:
- National Science Foundation
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