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Title: Cartesian Operator Factorization Method for Hydrogen
We generalize Schrödinger’s factorization method for Hydrogen from the conventional separation into angular and radial coordinates to a Cartesian-based factorization. Unique to this approach is the fact that the Hamiltonian is represented as a sum over factorizations in terms of coupled operators that depend on the coordinates and momenta in each Cartesian direction. We determine the eigenstates and energies, the wavefunctions in both coordinate and momentum space, and we also illustrate how this technique can be employed to develop the conventional confluent hypergeometric equation approach. The methodology developed here could potentially be employed for other Hamiltonians that can be represented as the sum over coupled Schrödinger factorizations.  more » « less
Award ID(s):
1915130 1747426
NSF-PAR ID:
10343033
Author(s) / Creator(s):
; ;
Date Published:
Journal Name:
Atoms
Volume:
10
Issue:
1
ISSN:
2218-2004
Page Range / eLocation ID:
14
Format(s):
Medium: X
Sponsoring Org:
National Science Foundation
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