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1. Low leakage current in heteroepitaxial ${\mathrm{Al}}_{0.7}{\mathrm{Sc}}_{0.3}\mathrm{N}$ ferroelectric films on $\mathrm{Ga}\mathrm{N}$

   https://doi.org/10.1103/PhysRevApplied.23.014036  

   Yazawa, Keisuke; Evans, Charles; Dickey, Elizabeth C; Tellekamp, M Brooks; Brennecka, Geoff L; Zakutayev, Andriy (January 2025, Physical Review Applied)

   Wurtzite $(\mathrm{Al},\mathrm{Sc})\mathrm{N}$ferroelectrics are attractive for microelectronics applications due to their chemical and structural compatibility with wurtzite semiconductors, such as $\mathrm{Ga}\mathrm{N}$and $(\mathrm{Al},\mathrm{Ga})\mathrm{N}$. However, the leakage current in epitaxial stacks reported to date should be reduced for reliable device operation. Here, we demonstrate low leakage current in epitaxial ${\mathrm{Al}}_{0.7}{\mathrm{Sc}}_{0.3}\mathrm{N}$films on $\mathrm{Ga}\mathrm{N}$with well-saturated ferroelectric hysteresis loops that are orders of magnitude lower (i.e., 0.07 A ${\mathrm{cm}}^{-2}$) than previously reported films (1–19 A ${\mathrm{cm}}^{-2}$) having similar or better structural characteristics. We also show that, for these high-quality epitaxial $(\mathrm{Al},\mathrm{Sc})\mathrm{N}$films, structural quality (edge and screw dislocations), as measured by diffraction techniques, is not the dominant contributor to leakage. Instead, the small leakage in our films is limited by thermionic emission across the interfaces, which is distinct from the large leakage due to trap-mediated bulk transport in the previously reported $(\mathrm{Al},\mathrm{Sc})\mathrm{N}$films. To support this conclusion, we show that ${\mathrm{Al}}_{0.7}{\mathrm{Sc}}_{0.3}\mathrm{N}$on lattice-matched ${\mathrm{In}}_{0.18}{\mathrm{Ga}}_{0.82}\mathrm{N}$buffers with improved structural characteristics but higher interface roughness exhibit increased leakage characteristics. This demonstration of low leakage current in heteroepitaxial $(\mathrm{Al},\mathrm{Sc})\mathrm{N}$films and understanding of the importance of interface barrier and surface roughness can guide further efforts toward improving the reliability of wurtzite ferroelectric devices. Published by the American Physical Society2025 

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2. Convolution identities for divisor sums and modular forms

   https://doi.org/10.1073/pnas.2322320121  

   Fedosova, Ksenia; Klinger-Logan, Kim; Radchenko, Danylo (October 2024, Proceedings of the National Academy of Sciences)

   Ribet, Kenneth (Ed.)

   We consider certain convolution sums that are the subject of a conjecture by Chester, Green, Pufu, Wang, and Wen in string theory. We prove a generalized form of their conjecture, explicitly evaluating absolutely convergent sums $\sum _{n_1\in \mathbb{Z}\setminus \{0,n\}}\phi (n_1,n-n_1){\sigma }_{2m_1}\left(n_1\right){\sigma }_{2m_2}(n-n_1),$ where $\phi (n_1,n_2)$is a Laurent polynomial with logarithms. Contrary to original expectations, such convolution sums, suitably extended to $n_1\in \{0,n\}$, do not vanish, but instead, they carry number theoretic meaning in the form of Fourier coefficients of holomorphic cusp forms. 

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3. Global reconstruction reduces the uncertainty of oceanic nitrous oxide emissions and reveals a vigorous seasonal cycle

   https://doi.org/10.1073/pnas.1921914117  

   Yang, Simon; Chang, Bonnie X.; Warner, Mark J.; Weber, Thomas S.; Bourbonnais, Annie M.; Santoro, Alyson E.; Kock, Annette; Sonnerup, Rolf E.; Bullister, John L.; Wilson, Samuel T.; et al (May 2020, Proceedings of the National Academy of Sciences)

   Assessment of the global budget of the greenhouse gas nitrous oxide ( ${\mathrm{N}}_2$O) is limited by poor knowledge of the oceanic ${\mathrm{N}}_2$O flux to the atmosphere, of which the magnitude, spatial distribution, and temporal variability remain highly uncertain. Here, we reconstruct climatological ${\mathrm{N}}_2$O emissions from the ocean by training a supervised learning algorithm with over 158,000 ${\mathrm{N}}_2$O measurements from the surface ocean—the largest synthesis to date. The reconstruction captures observed latitudinal gradients and coastal hot spots of ${\mathrm{N}}_2$O flux and reveals a vigorous global seasonal cycle. We estimate an annual mean ${\mathrm{N}}_2$O flux of 4.2 ± 1.0 Tg N $\cdot {\mathrm{y}}^{-1}$, 64% of which occurs in the tropics, and 20% in coastal upwelling systems that occupy less than 3% of the ocean area. This ${\mathrm{N}}_2$O flux ranges from a low of 3.3 ± 1.3 Tg N $\cdot {\mathrm{y}}^{-1}$in the boreal spring to a high of 5.5 ± 2.0 Tg N $\cdot {\mathrm{y}}^{-1}$in the boreal summer. Much of the seasonal variations in global ${\mathrm{N}}_2$O emissions can be traced to seasonal upwelling in the tropical ocean and winter mixing in the Southern Ocean. The dominant contribution to seasonality by productive, low-oxygen tropical upwelling systems (>75%) suggests a sensitivity of the global ${\mathrm{N}}_2$O flux to El Niño–Southern Oscillation and anthropogenic stratification of the low latitude ocean. This ocean flux estimate is consistent with the range adopted by the Intergovernmental Panel on Climate Change, but reduces its uncertainty by more than fivefold, enabling more precise determination of other terms in the atmospheric ${\mathrm{N}}_2$O budget. 

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4. Characterizing the fundamental bending vibration of a linear polyatomic molecule for symmetry violation searches

   https://doi.org/10.1088/1367-2630/ace471  

   Jadbabaie, Arian; Takahashi, Yuiki; Pilgram, Nickolas H; Conn, Chandler J; Zeng, Yi; Zhang, Chi; Hutzler, Nicholas R (July 2023, New Journal of Physics)

   Abstract Polyatomic molecules have been identified as sensitive probes of charge-parity violating and parity violating physics beyond the Standard Model (BSM). For example, many linear triatomic molecules are both laser-coolable and have parity doublets in the ground electronic $\tilde{X}{}^2{\mathrm{\Sigma }}^{+}\left(010\right)$state arising from the bending vibration, both features that can greatly aid BSM searches. Understanding the $\tilde{X}{}^2{\mathrm{\Sigma }}^{+}\left(010\right)$state is a crucial prerequisite to precision measurements with linear polyatomic molecules. Here, we characterize the fundamental bending vibration of ${}^{174}$YbOH using high-resolution optical spectroscopy on the nominally forbidden $\tilde{X}{}^2{\mathrm{\Sigma }}^{+}\left(010\right)$ $\to \tilde{A}{}^2{\mathrm{\Pi }}_{1/2}\left(000\right)$transition at 588 nm. We assign 39 transitions originating from the lowest rotational levels of the $\tilde{X}{}^2{\mathrm{\Sigma }}^{+}\left(010\right)$state, and accurately model the state’s structure with an effective Hamiltonian using best-fit parameters. Additionally, we perform Stark and Zeeman spectroscopy on the $\tilde{X}{}^2{\mathrm{\Sigma }}^{+}\left(010\right)$state and fit the molecule-frame dipole moment to $D_{\mathrm{m}\mathrm{o}\mathrm{l}}=2.16\left(1\right)$Dand the effective electrong-factor to $g_S=2.07\left(2\right)$. Further, we use an empirical model to explain observed anomalous line intensities in terms of interference from spin–orbit and vibronic perturbations in the excited $\tilde{A}{}^2{\mathrm{\Pi }}_{1/2}\left(000\right)$state. Our work is an essential step toward searches for BSM physics in YbOH and other linear polyatomic molecules. 

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5. Quantum group intertwiner space from quantum curved tetrahedron

   https://doi.org/10.1088/1361-6382/ad5f71  

   Han, Muxin; Hsiao, Chen-Hung; Pan, Qiaoyin (July 2024, Classical and Quantum Gravity)

   Abstract In this paper, we develop a quantum theory of homogeneously curved tetrahedron geometry, by applying the combinatorial quantization to the phase space of tetrahedron shapes defined in Haggardet al(2016Ann. Henri Poincaré172001–48). Our method is based on the relation between this phase space and the moduli space of SU(2) flat connections on a 4-punctured sphere. The quantization results in the physical Hilbert space as the solution of the quantum closure constraint, which quantizes the classical closure condition $M_4{M}_3{M}_2{M}_1=1$, $M_{\nu }\in \mathrm{SU}\left(2\right)$, for the homogeneously curved tetrahedron. The quantum group $U_q\left(\mathfrak{su}\right(2\left)\right)$emerges as the gauge symmetry of a quantum tetrahedron. The physical Hilbert space of the quantum tetrahedron coincides with the Hilbert space of 4-valent intertwiners of $U_q\left(\mathfrak{su}\right(2\left)\right)$. In addition, we define the area operators quantizing the face areas of the tetrahedron and compute the spectrum. The resulting spectrum is consistent with the usual Loop-Quantum-Gravity area spectrum in the large spin regime but is different for small spins. This work closely relates to 3+1 dimensional Loop Quantum Gravity in presence of cosmological constant and provides a justification for the emergence of quantum group in the theory. 

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